{"id":"W2914611385","doi":"10.1021/acsomega.8b03410","title":"Benzotriazole as an Efficient Ligand in Cu-Catalyzed Glaser Reaction","year":2019,"lang":"en","type":"article","venue":"ACS Omega","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Science and Engineering Research Board; Canadian Institute of Steel Construction","keywords":"Benzotriazole; Ligand (biochemistry); Catalysis; Yield (engineering); Substrate (aquarium); Combinatorial chemistry; Coupling reaction; Chemistry; Base (topology); Reaction conditions; Organic chemistry; Materials science; Mathematics; Metallurgy; Receptor","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001940042,0.0001751136,0.0002132969,0.0001261522,0.00007348863,0.00009201318,0.000212126,0.0001770301,0.0001252289],"category_scores_gemma":[0.0001254404,0.0001868414,0.00006977476,0.0002891127,0.00004222332,0.0002707506,0.00007004006,0.0003174612,0.001515008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002470688,"about_ca_system_score_gemma":0.00009054883,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001033854,"about_ca_topic_score_gemma":0.0001966774,"domain_scores_codex":[0.9986748,0.000001100463,0.0002953921,0.0004398384,0.0002719784,0.0003169428],"domain_scores_gemma":[0.998837,0.0001122878,0.0001095521,0.0007709911,0.00005930455,0.0001108733],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009122984,0.0002945941,0.004849256,0.00003447588,0.00001659479,0.00001097438,0.0003573618,0.0004709788,0.993187,0.0001424127,0.00009266784,0.0004525299],"study_design_scores_gemma":[0.002100053,0.00002429988,0.005943852,0.00007121007,0.00003266917,0.00005343031,0.0006463488,0.002336258,0.9824944,0.0001883407,0.005759344,0.0003498102],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945554,0.00004365786,0.000001696198,0.0001046924,0.0003370625,0.0001344304,0.0000222668,0.000139877,0.004660947],"genre_scores_gemma":[0.9961816,0.000008965309,0.000007893858,0.00003213772,0.000160921,0.00002238515,0.000221755,0.00003854892,0.003325787],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01069254,"threshold_uncertainty_score":0.9992625,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01004868113595811,"score_gpt":0.2691912688333432,"score_spread":0.2591425876973851,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}