{"id":"W2914611385","doi":"10.1021/acsomega.8b03410","title":"Benzotriazole as an Efficient Ligand in Cu-Catalyzed Glaser Reaction","year":2019,"lang":"en","type":"article","venue":"ACS Omega","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Science and Engineering Research Board; Canadian Institute of Steel Construction","keywords":"Benzotriazole; Ligand (biochemistry); Catalysis; Yield (engineering); Substrate (aquarium); Combinatorial chemistry; Coupling reaction; Chemistry; Base (topology); Reaction conditions; Organic chemistry; Materials science; Mathematics; Metallurgy; Receptor","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002935648,0.0005514412,0.0004753024,0.0003236178,0.0004315476,0.0002324052,0.0009085685,0.0006400101,0.001951415],"category_scores_gemma":[0.0001860117,0.000216388,0.0002019917,0.0005177421,0.0002133368,0.0003998076,0.0005890126,0.0007280257,0.0016084],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003950574,"about_ca_system_score_gemma":0.000447945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001473786,"about_ca_topic_score_gemma":0.004092271,"domain_scores_codex":[0.9996868,0.00005492802,0.00002298527,0.00007065608,0.00005649119,0.0001081326],"domain_scores_gemma":[0.999963,0.00000412335,0.000008862369,0.000006058713,0.000005758599,0.00001227055],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001651269,0.0001250319,0.0002253697,0.0006414232,0.00003132311,0.0008858434,0.0001584351,0.0005514855,0.9765542,0.002764029,0.002357087,0.01554077],"study_design_scores_gemma":[0.0000527432,0.0005111176,0.0006116611,0.00002867625,0.00004207678,0.0006746978,0.00004095542,0.001951345,0.9786375,0.0002224113,0.0171861,0.0000405752],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8206298,0.01585915,0.1195112,0.001219019,0.0005740181,0.0005419767,0.001034348,0.003314768,0.03731567],"genre_scores_gemma":[0.9656247,0.004558461,0.01790956,0.0001490241,0.00004706617,0.0001595216,0.0004449114,0.00008388451,0.01102267],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001951415,"threshold_uncertainty_score":0.006528199,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01004868113595811,"score_gpt":0.2691912688333432,"score_spread":0.2591425876973851,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}