{"id":"W2914779866","doi":"10.3390/catal9020140","title":"Palladium Comprising Dicationic Bipyridinium Supported Periodic Mesoporous Organosilica (PMO): Pd@Bipy–PMO as an Efficient Hybrid Catalyst for Suzuki–Miyaura Cross-Coupling Reaction in Water","year":2019,"lang":"en","type":"article","venue":"Catalysts","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Science Foundation of Shandong Province","keywords":"Catalysis; Palladium; Mesoporous material; Ionic liquid; Fourier transform infrared spectroscopy; Desorption; Materials science; Chemical engineering; Mesoporous organosilica; Adsorption; Heterogeneous catalysis; Inorganic chemistry; Chemistry; Mesoporous silica; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008721519,0.0007070786,0.0008593189,0.0004648179,0.0006635558,0.0006352311,0.0008098003,0.0004222765,0.0005313531],"category_scores_gemma":[0.0003042959,0.0006958954,0.000371955,0.0005285188,0.000352195,0.0006080726,0.0002401528,0.0007498843,0.001206186],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001533449,"about_ca_system_score_gemma":0.0005067276,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001529153,"about_ca_topic_score_gemma":0.0002314999,"domain_scores_codex":[0.99485,0.00000385457,0.001389794,0.001723474,0.0007225433,0.001310281],"domain_scores_gemma":[0.996052,0.000289272,0.0005163674,0.002213306,0.0005071919,0.0004218639],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002648922,0.0005518065,0.01077496,0.0003870219,0.0001096726,0.00004400775,0.001454997,0.003328854,0.9826909,0.00003282313,0.000150081,0.0002100115],"study_design_scores_gemma":[0.00265745,0.00007337048,0.005444511,0.000148713,0.0001812925,0.0003821924,0.0007208067,0.02174633,0.9653456,0.00005803154,0.002313571,0.0009280961],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965807,0.0001758899,0.00005366474,0.0002626696,0.0008727878,0.001039369,0.0002029909,0.0005133961,0.0002985156],"genre_scores_gemma":[0.9878264,0.00001542557,0.00002704148,0.0000655195,0.0003880514,0.0002564729,0.00982472,0.0002220359,0.001374347],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01841748,"threshold_uncertainty_score":0.9995715,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01102378382073925,"score_gpt":0.2819161902850935,"score_spread":0.2708924064643542,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}