{"id":"W2916661859","doi":"10.1021/acs.chemmater.8b04987","title":"Stabilizing Sulfur Cathode in Carbonate and Ether Electrolytes: Excluding Long-Chain Lithium Polysulfide Formation and Switching Lithiation/Delithiation Route","year":2019,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Light Source (Canada); Western University","funders":"Western University; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Polysulfide; Electrolyte; Cathode; Propylene carbonate; Inorganic chemistry; Ether; Carbonate; Nucleophile; Sulfur; Chemistry; Dissolution; Heteroatom; Materials science; Chemical engineering; Organic chemistry; Electrode; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003922834,0.0001726574,0.0003092297,0.0000598679,0.00002690911,0.00006231094,0.00007551664,0.0001502784,0.00001993057],"category_scores_gemma":[0.00006861539,0.000173952,0.00001294144,0.000071496,0.00002157403,0.0003363273,0.00005675035,0.00008838459,0.000001240024],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007426695,"about_ca_system_score_gemma":0.000008063397,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004554135,"about_ca_topic_score_gemma":0.000006467549,"domain_scores_codex":[0.9990406,0.00002150672,0.0004364938,0.0001903616,0.00009502692,0.0002159963],"domain_scores_gemma":[0.9995826,0.00005705282,0.0001398029,0.0001695274,0.00002768934,0.00002332703],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001854584,0.000004521486,0.001865039,0.0009621675,0.000008275008,8.11651e-7,0.0004529141,0.0007373439,0.9954152,0.00004643733,0.000001532857,0.000487208],"study_design_scores_gemma":[0.0003418077,0.00001130728,0.004146121,0.0002011465,0.000007665398,0.00001024898,0.0002437633,0.001267756,0.9924741,0.001101796,0.00001662279,0.0001776483],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978835,0.0005045066,0.0009054446,0.0000582782,0.0001113322,0.0001853281,0.000020314,0.0001583887,0.0001729063],"genre_scores_gemma":[0.998486,0.0002022907,0.001172074,0.000009341064,0.00003577674,0.00002054554,0.000022557,0.00002711768,0.00002422948],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002941087,"threshold_uncertainty_score":0.7093555,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006712972573764306,"score_gpt":0.2022423694096651,"score_spread":0.1955293968359008,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}