{"id":"W2917122724","doi":"10.1177/1469066718800844","title":"Ligation kinetics as a probe for gas-phase ligand field effects: Ligation of atomic transition metal cations with ammonia at room temperature","year":2019,"lang":"en","type":"article","venue":"European Journal of Mass Spectrometry","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Dissociation (chemistry); Argon; Helium; Ion; Kinetics; Analytical Chemistry (journal); Inductively coupled plasma; Atomic physics; Plasma; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004816141,0.000235352,0.0001836872,0.0001466358,0.0001911592,0.0004522337,0.0003051682,0.0003145669,0.001138058],"category_scores_gemma":[0.001122747,0.0001604935,0.0001444767,0.0002051277,0.0004067491,0.000423495,0.0001787876,0.0005082626,0.0003230199],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003621051,"about_ca_system_score_gemma":0.00016637,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009608041,"about_ca_topic_score_gemma":0.000853436,"domain_scores_codex":[0.9997867,0.00005631162,0.000009294179,0.00005286321,0.00005270454,0.00004221256],"domain_scores_gemma":[0.9994873,0.0002370202,0.0001188275,0.00003519065,0.00008169768,0.00003998209],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002219291,0.0000199507,0.0009104836,0.00002577161,0.000009553537,0.00002242333,0.00007850596,0.0002187948,0.9974564,0.00007297503,0.00002980529,0.0009335621],"study_design_scores_gemma":[0.000005679382,0.0002002861,0.00227652,0.000001992989,0.000005184661,0.00003507263,0.00003426214,0.002198595,0.9948421,0.00003877779,0.0003552454,0.000006307695],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922489,0.000373703,0.005995081,0.00006575762,0.00001137978,0.00001824227,0.0001790996,0.0001038448,0.00100418],"genre_scores_gemma":[0.9968212,0.0001852174,0.001928254,0.00001968836,0.000003939106,0.00001690582,0.0001437565,0.00002010996,0.0008609384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001138058,"threshold_uncertainty_score":0.003807187,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003723565028551987,"score_gpt":0.2263698054162477,"score_spread":0.2226462403876957,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}