{"id":"W2917342273","doi":"10.1021/acs.inorgchem.8b03399","title":"Tuning the Metal/Chalcogen Composition in Copper(I)–Chalcogenide Clusters with Cyclic (Alkyl)(amino)carbene Ligands","year":2019,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Chalcogen; Chalcogenide; Carbene; Copper; Alkyl; Ligand (biochemistry); Metal; Crystallography; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000255757,0.0004595367,0.0005837895,0.00006032025,0.0001520836,0.0001064235,0.0007949215,0.0002294685,0.0122121],"category_scores_gemma":[0.0000321809,0.0003548517,0.0002219396,0.0005662431,0.0001379065,0.0001520622,0.0002778672,0.000494118,0.0001904381],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000278301,"about_ca_system_score_gemma":0.0001097288,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008365921,"about_ca_topic_score_gemma":0.00003727316,"domain_scores_codex":[0.9975864,0.00002192051,0.0005532002,0.0007325275,0.0005243114,0.0005816934],"domain_scores_gemma":[0.9981253,0.0002061547,0.0002613147,0.00119047,0.00006627741,0.0001504432],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005770337,0.0001228505,0.007987501,0.0001820347,0.0002484889,0.00002582358,0.0003759228,0.00005296783,0.9894462,0.00001293215,0.00003032921,0.001457225],"study_design_scores_gemma":[0.001098225,0.00001662541,0.001240027,0.0001519964,0.0002200359,0.0001965358,0.001457433,0.0005234792,0.9924889,0.00003074665,0.002031534,0.0005444755],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.971182,0.0006719415,0.00001302924,0.0004435627,0.00004732967,0.0001329443,0.00003071847,0.0001212918,0.02735715],"genre_scores_gemma":[0.9955785,0.00005677948,0.00004425558,0.0001408497,0.0002102247,0.00003731048,0.0001666492,0.00009111595,0.003674297],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02439648,"threshold_uncertainty_score":0.9998903,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007698662664770642,"score_gpt":0.1973432543586102,"score_spread":0.1896445916938395,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}