{"id":"W2917785608","doi":"10.1021/acscatal.9b00336","title":"Palladium-Catalyzed Stereospecific <i>C</i>-Glycosylation of Glycals with Vinylogous Acceptors","year":2019,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; University at Albany; Ryerson University; State University of New York","keywords":"Stereoselectivity; Glycosylation; Palladium; Stereospecificity; Chemistry; Catalysis; Glycoside; Substrate (aquarium); Stereochemistry; Functional group; Combinatorial chemistry; Organic chemistry; Biology; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001192605,0.0002851775,0.0005379218,0.00008664155,0.00005667282,0.00004631405,0.0004199479,0.0001915844,0.004421157],"category_scores_gemma":[0.00005070843,0.0002464135,0.0002040359,0.0004545359,0.00009861048,0.0002000647,0.00008831643,0.000157606,0.0002097071],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008634535,"about_ca_system_score_gemma":0.00005317971,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001085978,"about_ca_topic_score_gemma":0.00002464556,"domain_scores_codex":[0.9982924,0.00001535031,0.0004605414,0.0005086483,0.0004132655,0.0003097364],"domain_scores_gemma":[0.9981384,0.0001897946,0.0003297116,0.00110342,0.0001248689,0.0001138218],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002047271,0.0001047985,0.01867545,0.0002007028,0.000301016,0.000008183562,0.0003280049,0.00009792048,0.9768421,0.00001809141,0.00007494586,0.003144034],"study_design_scores_gemma":[0.0006079864,0.00001598679,0.0007248835,0.00005421373,0.000224877,0.00001093518,0.0003700664,0.00006061748,0.9957059,0.00002372793,0.001876609,0.0003242147],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9742243,0.0001148386,0.00002083414,0.00004443639,0.00005430034,0.00008622017,0.00007279823,0.00007982016,0.0253024],"genre_scores_gemma":[0.996259,0.00003497082,0.0001115961,0.000014154,0.00008989726,0.00002138622,0.0005530486,0.00004442662,0.002871559],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02243084,"threshold_uncertainty_score":0.9999988,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0066441373158569,"score_gpt":0.1935317373529631,"score_spread":0.1868876000371062,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}