{"id":"W2921007396","doi":"10.1002/ejoc.201900104","title":"A Direct Brønsted Acid‐Catalyzed Azidation of Benzhydrols and Carbohydrates","year":2019,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Ontario Tech University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Brønsted–Lowry acid–base theory; Amide; Azide; Amine gas treating; Aldehyde; Catalysis; Alcohol; Organic chemistry; Functional group; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002904121,0.0001792882,0.0003234098,0.00002073929,0.000042493,0.0000313585,0.0003450586,0.00006029184,0.002877177],"category_scores_gemma":[0.0001870931,0.0001727294,0.0001111575,0.0001675941,0.0000756036,0.00009634902,0.0001012041,0.0002802802,0.00002525092],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000375601,"about_ca_system_score_gemma":0.00006776919,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":7.959021e-7,"about_ca_topic_score_gemma":1.441945e-7,"domain_scores_codex":[0.9987575,0.00002271012,0.0006339886,0.0002122406,0.0002165459,0.0001570197],"domain_scores_gemma":[0.9983389,0.00008260398,0.0009021829,0.0003831081,0.0001529268,0.0001403237],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003672972,0.00007703764,0.001137355,0.0002562907,0.00008270917,0.00001570454,0.0001749211,0.000004555459,0.9973191,0.000001649188,0.0001007786,0.0007931903],"study_design_scores_gemma":[0.000987742,0.00001313526,0.0002566694,0.0001761664,0.00007607364,0.0002211643,0.0002065072,0.00002257559,0.9954309,0.00001214778,0.002434447,0.0001625098],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9539483,0.0004280165,0.00002451283,0.0001051954,0.00002529103,0.00002971845,0.00002173919,0.00002392773,0.04539325],"genre_scores_gemma":[0.9980862,0.00008895035,0.0001054286,0.00001178959,0.0002053499,6.130126e-7,0.00003524572,0.00003888947,0.00142752],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04413787,"threshold_uncertainty_score":0.9980343,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006204315589979694,"score_gpt":0.1993480278867766,"score_spread":0.1931437122967969,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}