{"id":"W2923334817","doi":"10.1007/s12039-019-1609-6","title":"Synthesis of Fe and Cu metal complexes derived from ‘SNS’ Pincer type ligands and their efficient catalyst precursors for the chemical fixation of $$\\hbox {CO}_{2}$$ CO 2","year":2019,"lang":"en","type":"article","venue":"Journal of Chemical Sciences","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":25,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"","keywords":"Crystallography; Pincer movement; Chemistry; Pyridine; Denticity; Ligand (biochemistry); Catalysis; Stereochemistry; Metal; Crystal structure; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007778086,0.0001977218,0.0001414884,0.0001598764,0.000170117,0.0002689876,0.0002814681,0.0002856925,0.001514818],"category_scores_gemma":[0.000156939,0.0001564762,0.00008280359,0.0001299874,0.000118359,0.0001884633,0.0002121071,0.0002149576,0.000265843],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002228585,"about_ca_system_score_gemma":0.0001345154,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005336402,"about_ca_topic_score_gemma":0.001314139,"domain_scores_codex":[0.9999466,0.000008924884,0.000003824973,0.00001106155,0.00001390677,0.00001565037],"domain_scores_gemma":[0.9999728,0.000004381656,0.000006632471,0.00000369178,0.000005873455,0.000006615718],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002837725,0.00003599342,0.0001884964,0.0002492965,0.00001683412,0.0002129874,0.00009336117,0.0005680475,0.9862205,0.002673004,0.0006515004,0.008806187],"study_design_scores_gemma":[0.0000137604,0.00009004318,0.0003664616,0.000006383985,0.000007894982,0.00009617917,0.00001711963,0.001058543,0.9931244,0.00009043379,0.005121765,0.000006946642],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9811565,0.001405946,0.006263097,0.0001369726,0.00007079462,0.00004616145,0.0002136571,0.0001218163,0.01058514],"genre_scores_gemma":[0.9925579,0.000375303,0.00294342,0.00003063567,0.000005429664,0.00001868935,0.0001549319,0.00002317341,0.00389045],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001514818,"threshold_uncertainty_score":0.005067587,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01745410980982361,"score_gpt":0.2624338848226589,"score_spread":0.2449797750128353,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}