{"id":"W2926036315","doi":"10.1021/acs.chemrev.8b00514","title":"<i>N</i>-Heterocyclic Carbenes in Materials Chemistry","year":2019,"lang":"en","type":"review","venue":"Chemical Reviews","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":668,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Japan Society for the Promotion of Science; Natural Sciences and Engineering Research Council of Canada; Nagoya University; Queen's University; Canada Foundation for Innovation","keywords":"Chemistry; Nanotechnology; Surface modification; Organometallic chemistry; Combinatorial chemistry; Catalysis; Polymer; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002647121,0.0008370489,0.0005619708,0.001268708,0.0003176238,0.000749144,0.0005316495,0.0006648587,0.004570353],"category_scores_gemma":[0.0002821381,0.0001972627,0.0002233659,0.002028647,0.0004723397,0.001108431,0.0006280012,0.001541769,0.003850417],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006922085,"about_ca_system_score_gemma":0.0008321279,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008486656,"about_ca_topic_score_gemma":0.001828698,"domain_scores_codex":[0.9998696,0.00001806425,0.000009367118,0.00002860006,0.00005229883,0.00002200222],"domain_scores_gemma":[0.9998945,0.00004302341,0.00001430125,0.000005661529,0.00002725515,0.000015189],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00004321879,0.00007701123,0.0001306857,0.01462544,0.00004506399,0.0002000953,0.0001009654,0.0006005863,0.01095059,0.02913491,0.1019763,0.8421152],"study_design_scores_gemma":[0.000002570616,0.00003147695,0.0002212087,0.0007994208,0.00001095095,0.0002611379,0.00002139027,0.00006104235,0.0008947361,0.002580629,0.9951071,0.000008427295],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.0002974371,0.9869652,0.0003685698,0.0003454324,0.00118954,0.000008632283,0.00003320621,0.00002399505,0.01076802],"genre_scores_gemma":[0.00241878,0.9898173,0.0005208141,0.0004051738,0.0006056294,0.00001540202,0.00005834249,0.000005127951,0.006153339],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.004570353,"threshold_uncertainty_score":0.01528937,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05678658245843943,"score_gpt":0.3266566319506968,"score_spread":0.2698700494922574,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}