{"id":"W2927944263","doi":"10.1002/anie.201903354","title":"A Redox‐Confused Bismuth(I/III) Triamide with a T‐Shaped Planar Ground State","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":96,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Dalhousie University","keywords":"Bismuth; Pnictogen; Chemistry; Reactivity (psychology); Oxidation state; Electrophile; Redox; Crystallography; Ground state; Planar; Ligand (biochemistry); Oxide; Coordination geometry; Inorganic chemistry; Stereochemistry; Molecule; Metal; Organic chemistry; Hydrogen bond; Physics; Condensed matter physics; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006408499,0.0002174345,0.0001020389,0.0001333014,0.0001118519,0.0002733508,0.0003992405,0.000221194,0.001351148],"category_scores_gemma":[0.00009859541,0.000115895,0.0001094934,0.0001258213,0.0001443193,0.0002062419,0.0001729984,0.0002115442,0.0003600481],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002163872,"about_ca_system_score_gemma":0.000142181,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007128427,"about_ca_topic_score_gemma":0.000635531,"domain_scores_codex":[0.9999381,0.000007376072,0.000004087908,0.00001528487,0.00001412841,0.00002092878],"domain_scores_gemma":[0.9999541,0.000004365957,0.00001463707,0.000005674072,0.000008398036,0.00001282338],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008516439,0.00001247715,0.0000566871,0.0000274901,0.00000394173,0.0001000724,0.00002131404,0.0001091953,0.9977888,0.0004932361,0.00006699366,0.001234678],"study_design_scores_gemma":[0.00001102533,0.0002009609,0.0002599821,0.000002443641,0.000006422405,0.0001531429,0.00001164116,0.0006035329,0.9971225,0.00004533158,0.001579381,0.000003632173],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9865271,0.0002612582,0.004320878,0.00006085611,0.0000302255,0.00003219579,0.0001859093,0.0001712664,0.008410269],"genre_scores_gemma":[0.9948573,0.0001058541,0.002653446,0.00001721222,0.000003254565,0.00001219533,0.0001684715,0.00001979571,0.002162653],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001351148,"threshold_uncertainty_score":0.004520059,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01209744828696242,"score_gpt":0.2213379368851193,"score_spread":0.2092404885981568,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}