{"id":"W2928299385","doi":"10.1002/slct.201900190","title":"Synthesis, Structures and Lewis‐Acid‐Induced Isomerization of 8‐Methoxy[2.2]metaparacyclophanes and a DFT Study","year":2019,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Engineering and Physical Sciences Research Council; King Saud University; Compute Canada","keywords":"Isomerization; Chemistry; Benzene; Pyrene; Lewis acids and bases; Medicinal chemistry; Molecule; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001812734,0.0002570127,0.0004944802,0.00004005259,0.00007372098,0.00006311796,0.0001995875,0.000121346,0.0006821663],"category_scores_gemma":[0.0003353826,0.0002195112,0.00005460121,0.0001131816,0.00007033069,0.00009244595,0.00009933332,0.0001271791,0.000002949168],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001994219,"about_ca_system_score_gemma":0.00004031496,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004758736,"about_ca_topic_score_gemma":0.000002226405,"domain_scores_codex":[0.9987236,0.00003240773,0.0003631235,0.0004211354,0.0002393465,0.0002203763],"domain_scores_gemma":[0.9989195,0.0003055561,0.0002037219,0.0004249475,0.00006325403,0.00008302809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006592795,0.00008620439,0.0253587,0.000552794,0.0001337774,0.000001178041,0.0005061827,8.735864e-7,0.9596609,0.000007723975,0.0000168457,0.01360893],"study_design_scores_gemma":[0.0004491257,0.00006079181,0.006132366,0.00008129975,0.0001004781,0.00002521653,0.001132056,0.0001071234,0.99135,0.0001834382,0.0001220601,0.0002560457],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929993,0.001107903,0.000003568995,0.00003488962,0.00002997817,0.0001357094,0.000007347286,0.00004791283,0.005633445],"genre_scores_gemma":[0.9991494,0.0000727396,0.0003244645,0.000009735808,0.00005499653,0.00002733676,0.000006033617,0.00003033048,0.0003249102],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03168913,"threshold_uncertainty_score":0.8951409,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01295622732989039,"score_gpt":0.2323961983138881,"score_spread":0.2194399709839977,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}