{"id":"W2935319393","doi":"10.1021/jacs.9b02510","title":"Activation of H<sub>2</sub> and Et<sub>3</sub>SiH by the Borinium Cation [Mes<sub>2</sub>B]<sup>+</sup>: Avenues to Cations [MesB(μ-H)<sub>2</sub>(μ-Mes)BMes]<sup>+</sup> and [H<sub>2</sub>B(μ-H)(μ-Mes)B(μ-Mes)(μ-H)BH<sub>2</sub>]<sup>+</sup>","year":2019,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Boron; Salt (chemistry); Medicinal chemistry; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000937822,0.0002594094,0.0001433637,0.00009122854,0.0001578495,0.0002004746,0.0002627732,0.0002454308,0.008912942],"category_scores_gemma":[0.0001015888,0.0001354407,0.0001220381,0.0001038423,0.0001973462,0.0003595321,0.0003511754,0.0003355343,0.001461309],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002901526,"about_ca_system_score_gemma":0.0002318862,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006531336,"about_ca_topic_score_gemma":0.00177319,"domain_scores_codex":[0.999933,0.000006592505,0.000003478607,0.00001558473,0.00001702432,0.00002435147],"domain_scores_gemma":[0.9999691,0.000006016287,0.00000615243,0.000007024433,0.000004858875,0.000006719716],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003760901,0.00001881329,0.000259578,0.0001715515,0.00001178476,0.0001176166,0.00005858851,0.0002612591,0.9893685,0.002662727,0.0009754681,0.005718011],"study_design_scores_gemma":[0.00001960577,0.00009422704,0.0006287647,0.000006113461,0.000003784407,0.0001225215,0.00004361128,0.0005913602,0.9882995,0.0003066022,0.009876234,0.000007758119],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9533005,0.001760424,0.00807966,0.0004151489,0.0002991532,0.00008437417,0.001055588,0.0004423361,0.0345628],"genre_scores_gemma":[0.9853024,0.0005370528,0.001918679,0.00009763069,0.0000202738,0.0000272105,0.0004264256,0.00005337637,0.01161675],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008912942,"threshold_uncertainty_score":0.02981681,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006335885759279327,"score_gpt":0.2254342527415009,"score_spread":0.2190983669822216,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}