{"id":"W2935772641","doi":"10.1021/acs.jpcb.9b01168","title":"Initial Excited-State Structural Dynamics of dT and dA Oligonucleotide Homopentamers Using Resonance Raman Spectroscopy","year":2019,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Excited state; Nucleobase; Resonance Raman spectroscopy; Raman spectroscopy; Chemistry; Resonance (particle physics); Photochemistry; Spectroscopy; Atomic physics; DNA; Optics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001975524,0.0001708635,0.0001334279,0.0001640515,0.0001459828,0.0002413124,0.0002462026,0.000198536,0.001109478],"category_scores_gemma":[0.0004158013,0.000189023,0.0001858754,0.0001285965,0.000222435,0.0004479894,0.0001412507,0.000353046,0.0001582283],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000503336,"about_ca_system_score_gemma":0.0002531798,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001299944,"about_ca_topic_score_gemma":0.001278421,"domain_scores_codex":[0.9999356,0.000007306685,0.00000291997,0.00002370296,0.00001913685,0.0000113207],"domain_scores_gemma":[0.9998425,0.00007915607,0.00002200396,0.00001475215,0.00002572322,0.00001573479],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001402294,0.0001610752,0.002782053,0.0000597977,0.0000252333,0.00009554352,0.0002655093,0.05616758,0.928824,0.00386411,0.0001022551,0.007512662],"study_design_scores_gemma":[0.00001963691,0.0002187989,0.006305101,0.000008779808,0.00001545583,0.00006285178,0.00009139928,0.4927759,0.498374,0.00133099,0.0007592913,0.00003770098],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9900766,0.00006847817,0.008564652,0.00002236731,0.000004214931,0.00001411873,0.00005900571,0.00006082959,0.001129572],"genre_scores_gemma":[0.9940228,0.00007176342,0.005016222,0.00001024365,0.000001286331,0.00001786858,0.0001003064,0.00002265241,0.0007368623],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001299944,"threshold_uncertainty_score":0.003711581,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00569062657379203,"score_gpt":0.2586387063874203,"score_spread":0.2529480798136283,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}