{"id":"W2936950441","doi":"10.1021/acs.joc.9b00068","title":"Development of Palladium-Catalyzed Decarboxylative Allylation of Electron-Deficient Sulfones and Identification of Unusual Side Products","year":2019,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; Carleton University","keywords":"Chemistry; Protonation; Catalysis; Palladium; Substrate (aquarium); Tetrahydrofuran; Combinatorial chemistry; Trifluoromethyl; Organic chemistry; Alkyl; Solvent; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001202265,0.0001359187,0.0003341681,0.00004956799,0.00003381663,0.000006979245,0.0002418083,0.00008437312,0.0002986116],"category_scores_gemma":[0.0006310093,0.0001099506,0.00005589422,0.0003026389,0.0001055731,0.00008352004,0.000073269,0.0001594227,0.00000148247],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001268089,"about_ca_system_score_gemma":0.0005509396,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002735481,"about_ca_topic_score_gemma":0.000001270284,"domain_scores_codex":[0.9980377,0.00003097794,0.001150421,0.0001438105,0.0005192169,0.0001179034],"domain_scores_gemma":[0.9966534,0.000255886,0.001943988,0.0003184659,0.0007870163,0.00004119212],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000186145,0.00009850861,0.001054395,0.0005531336,0.0001478522,1.959379e-7,0.001699231,0.0001494086,0.9957709,0.00002144425,0.00001335837,0.0003053761],"study_design_scores_gemma":[0.0006340318,0.00001338498,0.003909728,0.0001070833,0.0001250752,0.00006064965,0.0008620491,0.00007192674,0.9939616,0.00008222371,0.00007846594,0.00009382102],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973276,0.0004278346,0.001654591,0.00007682486,0.00006948117,0.00007461654,0.000007918752,0.000005264591,0.0003559009],"genre_scores_gemma":[0.9980257,0.00005465196,0.001425504,0.000002350916,0.00007251879,7.984264e-7,0.00002866395,0.00001803202,0.0003717746],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002855333,"threshold_uncertainty_score":0.4483654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01273066804490712,"score_gpt":0.2529015959083271,"score_spread":0.2401709278634199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}