{"id":"W2938139243","doi":"10.71781/11249","title":"Copper and nickel catalysis for alkynylation reactions","year":2018,"lang":"en","type":"dissertation","venue":"Papyrus : Institutional Repository (Université de Montréal)","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal; Centre in Green Chemistry and Catalysis","keywords":"Alkynylation; Nickel; Copper; Catalysis; Chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts"],"consensus_categories":[],"category_scores_codex":[0.0001119169,0.0003703999,0.0003601416,0.0002511888,0.005962921,0.00009946719,0.0002216724,0.0005710106,0.0001124528],"category_scores_gemma":[0.0001397581,0.000455656,0.0003073643,0.0001899077,0.0002289858,0.0003014804,0.00006833978,0.0003235161,0.00004678364],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.003620975,"about_ca_system_score_gemma":0.0009308463,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01397375,"about_ca_topic_score_gemma":0.009825203,"domain_scores_codex":[0.9982168,0.000002260993,0.0003931551,0.0006783162,0.0003837759,0.0003257064],"domain_scores_gemma":[0.9982564,0.000159836,0.00043131,0.0005025368,0.0004299003,0.0002199742],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001708546,0.0004231495,0.003582961,0.001179912,0.001474715,0.0001843719,0.01893521,0.0003516388,0.9522526,0.004372172,0.008464548,0.007070215],"study_design_scores_gemma":[0.003085467,0.0001007248,0.008733734,0.0007476173,0.003059016,0.001301714,0.04489808,0.004959755,0.4770753,0.0008254921,0.4533647,0.001848335],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9697708,0.003125748,0.00007320185,0.0001047284,0.0007683192,0.0002563136,0.0003032969,0.0001967323,0.02540078],"genre_scores_gemma":[0.7317674,0.0002919099,0.0003082762,0.0000172018,0.0004467914,0.00009472462,0.006330951,0.00006321485,0.2606795],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4751772,"threshold_uncertainty_score":0.9997895,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006604691271961942,"score_gpt":0.2050700348607839,"score_spread":0.1984653435888219,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}