{"id":"W2938139243","doi":"10.71781/11249","title":"Copper and nickel catalysis for alkynylation reactions","year":2018,"lang":"en","type":"dissertation","venue":"Papyrus : Institutional Repository (Université de Montréal)","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal; Centre in Green Chemistry and Catalysis","keywords":"Alkynylation; Nickel; Copper; Catalysis; Chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000184829,0.0004183282,0.0002616252,0.0002428748,0.000304962,0.0003975341,0.0003229281,0.0003403726,0.002733043],"category_scores_gemma":[0.0002306721,0.0002354849,0.0002305493,0.0002786657,0.000224069,0.0002838252,0.000312401,0.0003469631,0.0009055837],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006558857,"about_ca_system_score_gemma":0.000443049,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00216561,"about_ca_topic_score_gemma":0.004803234,"domain_scores_codex":[0.9997042,0.00004432818,0.00002236469,0.0000734815,0.00009566564,0.0000599072],"domain_scores_gemma":[0.9999413,0.00001176466,0.0000115176,0.00001121862,0.00001647071,0.000007612198],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001700057,0.00002126242,0.0002394396,0.0004243007,0.00001748692,0.0001924351,0.0001497095,0.0006747321,0.9814745,0.001786458,0.0004311119,0.01441851],"study_design_scores_gemma":[0.0000100556,0.0001241947,0.0004513094,0.00001041394,0.00001276298,0.0001102457,0.00003587332,0.0006569021,0.9876872,0.0001145297,0.01077674,0.000009796246],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9228653,0.01219613,0.02133342,0.0002809014,0.0002146245,0.0003303982,0.0004192969,0.0005141458,0.04184574],"genre_scores_gemma":[0.9669727,0.004279501,0.00837215,0.00004512374,0.00001821886,0.0001095767,0.0002187514,0.00005616163,0.01992791],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002733043,"threshold_uncertainty_score":0.009142995,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006604691271961942,"score_gpt":0.2050700348607839,"score_spread":0.1984653435888219,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}