{"id":"W2939492691","doi":"10.1021/acs.inorgchem.9b00574","title":"Synthesis, Characterization, and Lewis Acid Behavior of [W(NC<sub>6</sub>F<sub>5</sub>)F<sub>4</sub>]<i><sub><i>x</i></sub></i> and Computational Study of W(NR)F<sub>4</sub> (R = H, F, CH<sub>3</sub>, CF<sub>3</sub>, C<sub>6</sub>H<sub>5</sub>, C<sub>6</sub>F<sub>5</sub>), W(NC<sub>6</sub>F<sub>5</sub>)F<sub>4</sub>(NCCH<sub>3</sub>), and W(NC<sub>6</sub>F<sub>5</sub>)F<sub>4</sub>(NC<sub>5</sub>H<sub>5</sub>)<i><sub><i>n</i></sub></i> (<i>n</i> = 1, 2)","year":2019,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; Compute Canada; University of Lethbridge","keywords":"Chemistry; Lewis acids and bases; Characterization (materials science); Crystallography; Stereochemistry; Nanotechnology; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity"],"category_scores_codex":[0.02490441,0.05076205,0.04471613,0.01887137,0.02139913,0.01526815,0.0322047,0.0380999,0.0004932083],"category_scores_gemma":[0.01196095,0.06037937,0.02283808,0.0392601,0.02385686,0.02322748,0.02654189,0.04789204,0.01165835],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.02477475,"about_ca_system_score_gemma":0.02332121,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007153967,"about_ca_topic_score_gemma":0.005847069,"domain_scores_codex":[0.8221608,0.0132433,0.04506561,0.04489768,0.03366068,0.04097195],"domain_scores_gemma":[0.8642065,0.01609304,0.03884435,0.03415147,0.02037953,0.0263251],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0153137,0.02493853,0.00937312,0.01718426,0.01995794,0.009194533,0.008044915,0.003511416,0.7867823,0.0004392849,0.03240952,0.07285047],"study_design_scores_gemma":[0.05122717,0.006818995,0.01411144,0.01520933,0.0248044,0.0150104,0.006539783,0.004205612,0.8075835,0.002595888,0.003016572,0.04887694],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8803484,0.01814841,0.002681567,0.003933528,0.01942286,0.03219732,0.02646709,0.01500899,0.001791782],"genre_scores_gemma":[0.8413731,0.07028224,0.0007164108,0.007360013,0.01815418,0.01361877,0.03004919,0.01832324,0.0001228562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05213383,"threshold_uncertainty_score":0.9963617,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006421899298741529,"score_gpt":0.1967609956964038,"score_spread":0.1903390963976622,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}