{"id":"W2939492691","doi":"10.1021/acs.inorgchem.9b00574","title":"Synthesis, Characterization, and Lewis Acid Behavior of [W(NC<sub>6</sub>F<sub>5</sub>)F<sub>4</sub>]<i><sub><i>x</i></sub></i> and Computational Study of W(NR)F<sub>4</sub> (R = H, F, CH<sub>3</sub>, CF<sub>3</sub>, C<sub>6</sub>H<sub>5</sub>, C<sub>6</sub>F<sub>5</sub>), W(NC<sub>6</sub>F<sub>5</sub>)F<sub>4</sub>(NCCH<sub>3</sub>), and W(NC<sub>6</sub>F<sub>5</sub>)F<sub>4</sub>(NC<sub>5</sub>H<sub>5</sub>)<i><sub><i>n</i></sub></i> (<i>n</i> = 1, 2)","year":2019,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; Compute Canada; University of Lethbridge","keywords":"Chemistry; Lewis acids and bases; Characterization (materials science); Crystallography; Stereochemistry; Nanotechnology; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005270572,0.0001575363,0.0001454182,0.000103345,0.0001704622,0.0001367993,0.0002214459,0.0001979608,0.001068865],"category_scores_gemma":[0.00009244969,0.00008569309,0.0001143543,0.0001491249,0.0001119867,0.0001917881,0.00007901211,0.000135808,0.0001349242],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001915052,"about_ca_system_score_gemma":0.0002135485,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002924763,"about_ca_topic_score_gemma":0.006010728,"domain_scores_codex":[0.9999663,0.000001327214,0.000001973254,0.000008615475,0.0000157996,0.000005952907],"domain_scores_gemma":[0.9999762,0.000002181084,0.000008610697,0.000002559228,0.000007421257,0.000003150054],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008346908,0.00001332218,0.0005762053,0.0001315167,0.000007742095,0.00006797731,0.00003914348,0.001594031,0.9930736,0.0004480581,0.0002214521,0.003743471],"study_design_scores_gemma":[0.000008032611,0.0001896583,0.003776453,0.00000536543,0.00001560723,0.00006395078,0.00006224534,0.007927464,0.9841654,0.00008642577,0.003687993,0.00001140058],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99479,0.0004112391,0.002227558,0.00003837056,0.0000094032,0.00002061088,0.0003058883,0.00005523801,0.002141788],"genre_scores_gemma":[0.9928342,0.0002679277,0.003289257,0.000013549,0.000002092503,0.00002109129,0.0003969153,0.00001463433,0.003160335],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002924763,"threshold_uncertainty_score":0.005815446,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006421899298741529,"score_gpt":0.1967609956964038,"score_spread":0.1903390963976622,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}