{"id":"W2940532648","doi":"10.1039/c9sc01357a","title":"Selective decontamination of the reactive air pollutant nitrous acid <i>via</i> node-linker cooperativity in a metal–organic framework","year":2019,"lang":"en","type":"article","venue":"Chemical Science","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University; Memorial University of Newfoundland","funders":"Research and Development Corporation of Newfoundland and Labrador; Natural Sciences and Engineering Research Council of Canada; Memorial University of Newfoundland; Government of Canada","keywords":"Human decontamination; Cooperativity; Nitrous acid; Linker; Pollutant; Metal-organic framework; Chemistry; Metal; Environmental chemistry; Environmental remediation; Nitrous oxide; Photochemistry; Environmental science; Inorganic chemistry; Waste management; Contamination; Organic chemistry; Adsorption; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004485677,0.0001765951,0.0003023248,0.00004238695,0.0001149887,0.0000271695,0.0007978,0.0002162045,0.00047135],"category_scores_gemma":[0.001270443,0.0001265054,0.00009252773,0.00155154,0.000482516,0.0002214425,0.0002238095,0.0006053887,0.00005014418],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003090177,"about_ca_system_score_gemma":0.0002319608,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000430969,"about_ca_topic_score_gemma":0.00001477757,"domain_scores_codex":[0.9982541,0.00003177414,0.0003349818,0.0005503249,0.0004780542,0.0003508012],"domain_scores_gemma":[0.9985538,0.0003145692,0.0002160905,0.0006598834,0.0001653983,0.00009025481],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008757494,0.0001559876,0.002700146,0.00001472912,0.000009526669,2.025565e-7,0.0003020739,0.000005323374,0.9942644,0.001444372,0.000006356089,0.001088161],"study_design_scores_gemma":[0.0001473372,0.000007025288,0.00412772,0.0000946513,0.00001665941,0.000004634425,0.0001293351,0.0009078321,0.9921986,0.002150998,0.00005605735,0.000159084],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9928241,0.00006672738,0.001722252,0.0004500854,0.00006345348,0.0002068566,0.00001383914,0.00002773831,0.004624906],"genre_scores_gemma":[0.9981907,0.000005383144,0.001392326,0.0002089952,0.00003319034,0.00003760829,0.000001653501,0.00001514094,0.0001150055],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005366555,"threshold_uncertainty_score":0.5160952,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007156273714632671,"score_gpt":0.2313930826790602,"score_spread":0.2242368089644275,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}