{"id":"W2940615051","doi":"10.1002/chem.201901882","title":"An H‐Substituted Rhodium Silylene","year":2019,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"Rhodium; Silylene; Chemistry; Cyclooctene; Oxidative addition; Hydride; Silylation; Medicinal chemistry; Reactivity (psychology); Ligand (biochemistry); Stereochemistry; Crystallography; Metal; Catalysis; Organic chemistry; Silicon","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004787265,0.0002851468,0.0003094528,0.00003404233,0.0001879451,0.0002774964,0.000886583,0.00005444479,0.1621653],"category_scores_gemma":[0.00004998955,0.0002645367,0.0002527286,0.0001520652,0.0000680238,0.0002193825,0.0001018733,0.000538162,0.001219366],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008213541,"about_ca_system_score_gemma":0.00007034292,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000118358,"about_ca_topic_score_gemma":1.3295e-7,"domain_scores_codex":[0.9982809,0.00006114794,0.0004782877,0.0004179021,0.0003500503,0.0004116816],"domain_scores_gemma":[0.998321,0.00003118705,0.00026899,0.0008532068,0.00009990785,0.000425685],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002642405,0.0001367472,0.0005770438,0.0000722297,0.00009247598,0.000168455,0.00009342845,0.00003275785,0.9833539,0.000005909936,0.0002584637,0.01518216],"study_design_scores_gemma":[0.001908409,0.00003610536,0.002214776,0.0001720201,0.0001995561,0.001932846,0.0008676209,0.001696434,0.6338263,0.00004876334,0.3560212,0.001075959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8453798,0.0002237109,0.0001075593,0.00009990516,0.0001016536,0.00001786775,0.00001491012,0.0001058846,0.1539488],"genre_scores_gemma":[0.9849208,0.00005508371,0.0003574481,0.00004822401,0.001008893,0.000001028751,0.0000544875,0.00007889336,0.01347515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3557628,"threshold_uncertainty_score":0.9999807,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009012329963768178,"score_gpt":0.2023531423251073,"score_spread":0.1933408123613392,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}