{"id":"W2942525890","doi":"10.1002/cssc.201900928","title":"Direct Synthesis of Diphenylamines from Phenols and Ammonium Formate Catalyzed by Palladium","year":2019,"lang":"en","type":"article","venue":"ChemSusChem","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds de Recherche du Québec - Santé; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; Canada Excellence Research Chairs, Government of Canada","keywords":"Palladium; Ammonium formate; Catalysis; Chemistry; Phenols; Formate; Ammonium; Organic chemistry; Formic acid","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001325463,0.0005925439,0.0001906629,0.0002295288,0.0001295277,0.0002339125,0.0003433476,0.0003166098,0.001696739],"category_scores_gemma":[0.0001355274,0.0002295888,0.0002052083,0.0001981644,0.000124284,0.0003228592,0.0002497547,0.0003696273,0.001018478],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002469664,"about_ca_system_score_gemma":0.000206378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000330822,"about_ca_topic_score_gemma":0.0008291336,"domain_scores_codex":[0.999893,0.00001249671,0.00001442524,0.00002401645,0.00002354894,0.00003246331],"domain_scores_gemma":[0.9999279,0.000008826077,0.00002148839,0.00001127276,0.00001215642,0.00001834701],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005510501,0.00003885828,0.00008962535,0.0003086532,0.00001692654,0.0002137782,0.00003879026,0.0002013799,0.9932174,0.0004326716,0.0001645381,0.005222377],"study_design_scores_gemma":[0.000009793723,0.0001157964,0.0002234837,0.00000512104,0.000009340878,0.0000915776,0.000007053541,0.0003301826,0.9957165,0.00004228942,0.003444903,0.000003924603],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9365139,0.005404069,0.03656407,0.0001929406,0.0001920081,0.0001756204,0.0008537715,0.0004406995,0.01966288],"genre_scores_gemma":[0.9796718,0.002138201,0.01164105,0.00004954985,0.0000133619,0.00003185846,0.0002867582,0.00004556391,0.00612192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001696739,"threshold_uncertainty_score":0.00567615,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005461948047982529,"score_gpt":0.210570647825642,"score_spread":0.2051086997776595,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}