{"id":"W2942673332","doi":"10.1002/cctc.201900550","title":"Hydrosilylative Reduction of Tertiary Amides to Amines Catalyzed by <i>N</i>‐(Phosphinoaryl)anilido Complexes of Iron and Cobalt","year":2019,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Hydrosilylation; Amide; Catalysis; Cobalt; Chemistry; Alkyl; Ligand (biochemistry); Medicinal chemistry; Redox; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009809485,0.0002023449,0.0004184423,0.0000968264,0.00003383061,0.00001075815,0.0002040378,0.0001234787,0.0003102129],"category_scores_gemma":[0.0000620033,0.0001997236,0.00009507273,0.0004592677,0.0001341257,0.000127335,0.0001086624,0.00009681289,0.00002443991],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006236674,"about_ca_system_score_gemma":0.00002303296,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002501523,"about_ca_topic_score_gemma":0.000002980014,"domain_scores_codex":[0.9987066,0.000008998873,0.0004401203,0.0003705294,0.0002865505,0.000187213],"domain_scores_gemma":[0.9990003,0.00007720124,0.0002810355,0.0003904867,0.0001330996,0.0001178803],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004410875,0.0001154781,0.007252549,0.0002979929,0.00006494038,2.776414e-7,0.001040387,0.000005705956,0.9869995,0.0000270977,0.001577001,0.00257499],"study_design_scores_gemma":[0.0005411025,0.00002068554,0.0006784035,0.000048157,0.00005808102,0.00000520732,0.001287213,0.00009901209,0.9963698,0.00004876382,0.0006440713,0.000199487],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947462,0.0007673728,0.00002507429,0.0001572764,0.00004037494,0.0001301869,0.0001157522,0.0000435339,0.003974197],"genre_scores_gemma":[0.9976822,0.00005679519,0.0002171486,0.00003749944,0.0000314075,0.0000151809,0.0002712266,0.00002460185,0.001663981],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009370345,"threshold_uncertainty_score":0.8144494,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005393236722212642,"score_gpt":0.2166933253117795,"score_spread":0.2113000885895669,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}