{"id":"W2943869213","doi":"10.1039/c9dt01148j","title":"Classifying donor strengths of dipyrrinato/aza-dipyrrinato ligands","year":2019,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Ligand (biochemistry); Nuclear magnetic resonance spectroscopy; Chemistry; Spectroscopy; Crystallography; Stereochemistry; Physics; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004129581,0.0002861,0.0001980531,0.0002244061,0.0001352048,0.0003871141,0.0003647778,0.0003142507,0.001842565],"category_scores_gemma":[0.0005971558,0.000155646,0.0001002761,0.0001981483,0.0001902554,0.0003733966,0.0001703502,0.0003170375,0.0004576436],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004505749,"about_ca_system_score_gemma":0.0002178234,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007088772,"about_ca_topic_score_gemma":0.001168906,"domain_scores_codex":[0.9997732,0.00003654645,0.00002121494,0.00005805067,0.0000686096,0.00004231747],"domain_scores_gemma":[0.9997464,0.00008355885,0.00004976178,0.00001941941,0.00005963009,0.0000412507],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008300046,0.00002724681,0.0002559648,0.00003386247,0.000003177824,0.00000883235,0.00001011644,0.0004143621,0.9971976,0.0001238704,0.00003686795,0.001805139],"study_design_scores_gemma":[0.000005241589,0.00009756946,0.000437501,0.000003109504,0.000006051847,0.0000193909,0.000009043692,0.003429625,0.9955841,0.00003557746,0.0003679163,0.000004971178],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9859449,0.0005861627,0.009221115,0.00008052112,0.00001249323,0.00005797828,0.0003673234,0.0001617616,0.003567846],"genre_scores_gemma":[0.9896966,0.0003349935,0.008414569,0.00004453961,0.000003688484,0.00005907037,0.0003146143,0.00002588266,0.001106096],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001842565,"threshold_uncertainty_score":0.006163955,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01149883524495525,"score_gpt":0.2508551077600188,"score_spread":0.2393562725150635,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}