{"id":"W2944569455","doi":"10.1055/s-0037-1611824","title":"New Zinc Catalyst for Hydrosilylation of Carbonyl Compounds","year":2019,"lang":"en","type":"article","venue":"Synthesis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Hydrosilylation; Allylic rearrangement; Catalysis; Zinc; Methanol; Organic chemistry; Reaction conditions","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001214118,0.0001046368,0.0002412761,0.0001120087,0.00003211168,0.0000124478,0.0001749356,0.00009314815,0.00135894],"category_scores_gemma":[0.0001602977,0.0001036591,0.0001758595,0.0002516423,0.00001553781,0.00006551576,0.00002384738,0.00003932495,0.00009051944],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005781582,"about_ca_system_score_gemma":0.00005738085,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001829024,"about_ca_topic_score_gemma":0.00001202428,"domain_scores_codex":[0.9991868,0.000007128366,0.0002540553,0.0002023962,0.0002108452,0.0001388002],"domain_scores_gemma":[0.9990445,0.0003306469,0.0001573408,0.0003445416,0.0000562997,0.00006666817],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009432868,0.0001365053,0.015299,0.0004793005,0.000469024,7.215428e-7,0.0004356614,0.0001882284,0.8364626,0.001956423,0.003505823,0.1409723],"study_design_scores_gemma":[0.0003005686,0.000008006275,0.0002886923,0.00002614175,0.0001272327,0.000001196865,0.0001301465,0.002554741,0.9839354,0.0001626558,0.01231307,0.0001521814],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.798658,0.0003284889,0.002710198,0.000271381,0.0001379207,0.0002079899,0.0001719837,0.0001169046,0.1973971],"genre_scores_gemma":[0.9930296,0.000005685451,0.0007864211,0.00001612216,0.00006906143,0.00001910381,0.00006186866,0.00002008926,0.005992042],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1943716,"threshold_uncertainty_score":0.999554,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009147959311688285,"score_gpt":0.2251491468920525,"score_spread":0.2160011875803642,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}