{"id":"W2945250366","doi":"10.1021/acs.inorgchem.8b03500","title":"Influence of Sulfur Oxidation State and Substituents on Sulfur-Bridged Luminescent Copper(I) Complexes Showing Thermally Activated Delayed Fluorescence","year":2019,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Engineering and Physical Sciences Research Council; University of St Andrews; AstraZeneca","keywords":"Chemistry; Diimine; Copper; Bimetallic strip; Photochemistry; Steric effects; Sulfur; Photoluminescence; Luminescence; Platinum; Metal; Inorganic chemistry; Catalysis; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000198336,0.0003619779,0.0001643565,0.0001144474,0.0001025916,0.0003068363,0.0002708177,0.0002016761,0.001177582],"category_scores_gemma":[0.0004206444,0.0001644237,0.0001092189,0.000166015,0.0001676734,0.000171332,0.000152119,0.0002151335,0.0001859371],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001891941,"about_ca_system_score_gemma":0.0001378456,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006977321,"about_ca_topic_score_gemma":0.0009502537,"domain_scores_codex":[0.9998543,0.00003095437,0.00001671102,0.00003270406,0.00002476331,0.00004052629],"domain_scores_gemma":[0.9998135,0.00005908031,0.00004806939,0.00001487201,0.00003102989,0.00003352924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004870667,0.00003642328,0.0002968009,0.00008132098,0.00001396271,0.00006374362,0.00006913637,0.0003072293,0.9962231,0.0001038818,0.00006947372,0.002247904],"study_design_scores_gemma":[0.000009039464,0.000269441,0.0007250545,0.00000494633,0.00001476737,0.00002863529,0.00002326197,0.0006118281,0.9977976,0.000008454747,0.0005025465,0.00000442308],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989084,0.0001913874,0.0002283575,0.00001130766,0.000005770119,0.000004917094,0.00003813625,0.00001998697,0.0005918121],"genre_scores_gemma":[0.998979,0.0001821318,0.0004365566,0.000009602482,0.000002550057,0.000006136856,0.00005619604,0.0000110561,0.0003168563],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001177582,"threshold_uncertainty_score":0.00393939,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01921107844111903,"score_gpt":0.2351614001128531,"score_spread":0.2159503216717341,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}