{"id":"W2945568498","doi":"10.1039/c8cs00826d","title":"The role of polysulfide dianions and radical anions in the chemical, physical and biological sciences, including sulfur-based batteries","year":2019,"lang":"en","type":"review","venue":"Chemical Society Reviews","topic":"Advanced Battery Materials and Technologies","field":"Engineering","cited_by":300,"is_retracted":false,"has_abstract":true,"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Polysulfide; Disproportionation; Chemistry; Sulfur; Dissociation (chemistry); Electron paramagnetic resonance; Radical ion; Electrochemistry; Inorganic chemistry; Raman spectroscopy; Photochemistry; Organic chemistry; Physical chemistry; Ion; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005703419,0.0003947708,0.001479787,0.00001980559,0.000150589,0.00007803084,0.0006143639,0.0003283176,0.000004311366],"category_scores_gemma":[0.0002572156,0.0001878764,0.0003887569,0.0003784372,0.001600855,0.00005974947,0.0003023985,0.0005771965,0.000004425101],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005100034,"about_ca_system_score_gemma":0.00003012271,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002450876,"about_ca_topic_score_gemma":2.657713e-7,"domain_scores_codex":[0.9983625,0.0001045204,0.0006356993,0.0003778326,0.0001422851,0.0003771701],"domain_scores_gemma":[0.9983111,0.001104147,0.0001674076,0.0003609987,0.000009494388,0.00004683328],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00000244805,0.00007697056,0.00004467173,0.009778226,0.00006558893,9.170914e-7,0.0001984288,0.00000132795,0.0445263,0.001719182,0.001024814,0.9425611],"study_design_scores_gemma":[0.0001002319,0.00002334891,0.000003202589,0.00275588,0.0001136066,0.00001501335,0.0001039527,0.00009347842,0.003368078,0.00100202,0.9921036,0.0003176398],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.01337722,0.9855784,0.00002837034,0.0001456324,0.00004650548,0.0006686352,0.00004148687,0.00006833229,0.00004542104],"genre_scores_gemma":[0.006337473,0.9924117,0.0008423151,0.00005991786,0.00008701963,0.0002115275,0.00002608428,0.00002306444,9.342577e-7],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9910787,"threshold_uncertainty_score":0.7661378,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06869939184964699,"score_gpt":0.3129608482143503,"score_spread":0.2442614563647033,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}