{"id":"W2945662132","doi":"10.1021/acs.orglett.9b00773","title":"Sodium Methyl Carbonate as an Effective C1 Synthon. Synthesis of Carboxylic Acids, Benzophenones, and Unsymmetrical Ketones","year":2019,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Synthon; Reactivity (psychology); Reagent; Carboxylic acid; Selectivity; Sodium; Sodium carbonate; Carbonate; Organic chemistry; Medicinal chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003764792,0.0007382435,0.0002335441,0.0003207738,0.0002591012,0.0002211605,0.0005108032,0.0003390262,0.002664157],"category_scores_gemma":[0.0002249577,0.0002186269,0.0001563645,0.0003661919,0.0003206998,0.0003814064,0.0003682918,0.0005709502,0.001170864],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004342636,"about_ca_system_score_gemma":0.0006798322,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001370366,"about_ca_topic_score_gemma":0.00313342,"domain_scores_codex":[0.9996718,0.00005587588,0.00002432181,0.00005559231,0.0001107556,0.00008166656],"domain_scores_gemma":[0.9998723,0.00001635698,0.00002054278,0.00001327202,0.00004012491,0.00003734931],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002034825,0.00003888991,0.0002600712,0.0004752594,0.00001603292,0.000403634,0.00005479227,0.0003755301,0.9828959,0.002440529,0.001447723,0.0113881],"study_design_scores_gemma":[0.00002780235,0.00021525,0.0004806829,0.0000105552,0.00001071986,0.0003377502,0.00001530249,0.0005050626,0.9865386,0.0001109202,0.01173411,0.00001335354],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8652316,0.02108499,0.04602681,0.002328967,0.001299102,0.0004126926,0.001529588,0.0006155439,0.06147075],"genre_scores_gemma":[0.9754755,0.006649453,0.01092859,0.0001796365,0.0000611922,0.00005571135,0.0005068867,0.00005041729,0.006092729],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002664157,"threshold_uncertainty_score":0.008912444,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004220493066730452,"score_gpt":0.2074838828751865,"score_spread":0.203263389808456,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}