{"id":"W2945800289","doi":"10.1002/9780470682531.pat0953","title":"Rearrangements and Fragmentations Mediated by Hypervalent Iodine Reagents","year":2018,"lang":"en","type":"other","venue":"","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Hypervalent molecule; Chemistry; Reagent; Aryl; Beckmann rearrangement; Enantioselective synthesis; Iodine; Diol; Stereochemistry; Combinatorial chemistry; Organic chemistry; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001691875,0.0005524492,0.0001744671,0.0004482942,0.0001889354,0.0003566679,0.0005128781,0.0002508824,0.003159878],"category_scores_gemma":[0.0001619863,0.0001403996,0.0002571385,0.0003345729,0.0003591017,0.0003553107,0.0005069934,0.0005386023,0.0006808943],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004873809,"about_ca_system_score_gemma":0.00024637,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005507672,"about_ca_topic_score_gemma":0.0007766444,"domain_scores_codex":[0.9997923,0.00002204814,0.000009563214,0.00004270643,0.00005504783,0.00007842319],"domain_scores_gemma":[0.9999537,0.000009226489,0.00001778752,0.000006511325,0.000005915769,0.000006832888],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002057306,0.00003601518,0.0003702008,0.0004031473,0.00004965116,0.000838516,0.0003429985,0.0008689705,0.965767,0.007665782,0.0009501794,0.02250182],"study_design_scores_gemma":[0.00001962753,0.00023999,0.0008565251,0.00003023912,0.0000387993,0.0006714507,0.00007715132,0.0004518674,0.9748918,0.0005453629,0.02215375,0.00002336092],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9093854,0.02031738,0.01517107,0.0002775586,0.0001942638,0.0000997328,0.0006049271,0.000462607,0.05348706],"genre_scores_gemma":[0.9849526,0.00565159,0.002151888,0.00008239826,0.00002645518,0.00002823963,0.0002735152,0.0000560419,0.006777253],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003159878,"threshold_uncertainty_score":0.01057082,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01270714907504666,"score_gpt":0.249729601816823,"score_spread":0.2370224527417763,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}