{"id":"W2946736697","doi":"10.1039/c9dt01788g","title":"Ligand mixed-valence and electrical conductivity in coordination complexes containing a redox-active phenalenol-substituted ligand","year":2019,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health; Brock University","funders":"Natural Sciences and Engineering Research Council of Canada; Brock University","keywords":"Redox; Valence (chemistry); Ligand (biochemistry); Chemistry; Conductivity; Coordination complex; Inorganic chemistry; Metal; Receptor; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001019761,0.0002693821,0.0002296713,0.0001371885,0.0001980378,0.0005347708,0.0004515378,0.0002703368,0.0009281036],"category_scores_gemma":[0.0002437027,0.0001169227,0.00006737024,0.000168724,0.0002802564,0.0001745788,0.0002492672,0.0002937885,0.0001299346],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002230583,"about_ca_system_score_gemma":0.00007800556,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000326536,"about_ca_topic_score_gemma":0.0004747328,"domain_scores_codex":[0.9999118,0.00001519416,0.000004602217,0.00002260786,0.00002406833,0.00002168201],"domain_scores_gemma":[0.9999244,0.0000216672,0.00001631314,0.000006886959,0.00001607507,0.00001455841],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006724663,0.00005256823,0.0006545374,0.0001910167,0.00002140282,0.000138515,0.0001153745,0.0003862322,0.9920182,0.001092908,0.0004025969,0.004254198],"study_design_scores_gemma":[0.00002272788,0.0002448677,0.001282041,0.000008044798,0.00001929479,0.0002323542,0.00005995758,0.002071704,0.9944851,0.0001550477,0.00140993,0.000008827784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956244,0.0007926307,0.001422218,0.00007198805,0.00001681786,0.000008481412,0.00009758504,0.00007279912,0.0018931],"genre_scores_gemma":[0.9983334,0.0001500956,0.000571301,0.00002074508,0.000003122704,0.000005636197,0.00008046419,0.00001153397,0.000823676],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009281036,"threshold_uncertainty_score":0.003104806,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01974521026707292,"score_gpt":0.2616168251207539,"score_spread":0.241871614853681,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}