{"id":"W2947909911","doi":"10.1002/chem.201902419","title":"Oxoborane Formation Turns on Formazanate‐Based Photoluminescence","year":2019,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Ontario Ministry of Research and Innovation","keywords":"Photoluminescence; Steric effects; Adduct; Ligand (biochemistry); Boron; Chemistry; Excited state; Density functional theory; Crystallography; Materials science; Photochemistry; Stereochemistry; Computational chemistry; Organic chemistry; Physics; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001296987,0.000197446,0.0001368255,0.0001213785,0.0001350123,0.0003363403,0.0002479805,0.0002763815,0.001809524],"category_scores_gemma":[0.0001528783,0.000124539,0.0000868231,0.00009291971,0.0002912081,0.0001848038,0.0001989671,0.0002476412,0.0002014061],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002798607,"about_ca_system_score_gemma":0.0001032137,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004067293,"about_ca_topic_score_gemma":0.0005427915,"domain_scores_codex":[0.9999079,0.0000166295,0.000004616577,0.00002051109,0.00002474329,0.00002554906],"domain_scores_gemma":[0.9999181,0.00002532204,0.00002154541,0.00000803339,0.00001009173,0.00001682892],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001069307,0.00001482649,0.0001174914,0.00004500175,0.000004026457,0.00005464497,0.0000445688,0.0001050094,0.9977538,0.0005569586,0.00005161223,0.001145174],"study_design_scores_gemma":[0.00001074526,0.0001301607,0.0002890583,0.000002680787,0.000002364162,0.00004159937,0.00001037818,0.0003501362,0.9984075,0.00003105116,0.0007215708,0.000002751834],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938133,0.0002521461,0.001982206,0.00003430519,0.00001232437,0.00001938012,0.00006801367,0.00007937345,0.003738999],"genre_scores_gemma":[0.9981279,0.00008150685,0.0008740645,0.00001011952,0.00000116306,0.000006024201,0.00003517095,0.00001211786,0.0008518696],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001809524,"threshold_uncertainty_score":0.006053507,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009919601373044457,"score_gpt":0.2061274201095932,"score_spread":0.1962078187365488,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}