{"id":"W2948149206","doi":"10.1039/c9cc04203b","title":"2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(<scp>v</scp>) oxidant","year":2019,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Winnipeg; University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Directorate for Mathematical and Physical Sciences; Russian Science Foundation; Royal Society","keywords":"Hypervalent molecule; Iodine; Chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001984298,0.0003366054,0.0002034964,0.0002111668,0.0001906557,0.0001775801,0.0003919986,0.0002616966,0.001334398],"category_scores_gemma":[0.00009653014,0.0001242276,0.0001180715,0.0002013011,0.0001975262,0.0001543563,0.0001985688,0.0004027978,0.0004347822],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004161221,"about_ca_system_score_gemma":0.0003207469,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001486441,"about_ca_topic_score_gemma":0.00208322,"domain_scores_codex":[0.999869,0.00001875043,0.000006420784,0.00002848316,0.00004024545,0.00003698784],"domain_scores_gemma":[0.9999539,0.000004472212,0.00001019037,0.000005800535,0.00001317019,0.00001264609],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008544615,0.000009451251,0.00009703477,0.00007590446,0.000004996425,0.00004043329,0.0000189698,0.00009192414,0.9969255,0.0003155894,0.0001582587,0.002176399],"study_design_scores_gemma":[0.000008638221,0.0000822205,0.0002517798,0.000002450452,0.000005653581,0.0000709251,0.000006647344,0.0001411772,0.9950544,0.00001863299,0.004354478,0.000002932094],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9519942,0.006774692,0.02589314,0.0003370245,0.00009584326,0.0001547105,0.0006958474,0.0004141805,0.01364029],"genre_scores_gemma":[0.9839219,0.00220908,0.008313973,0.00005800318,0.00001539544,0.00003949676,0.0005496268,0.00003557586,0.0048571],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001486441,"threshold_uncertainty_score":0.00446403,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01974967307591726,"score_gpt":0.2505712879869348,"score_spread":0.2308216149110175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}