{"id":"W2949079759","doi":"10.1021/ol703085f","title":"Total Syntheses of Clausamines A−C and Clausevatine D","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Marine Sponges and Natural Products","field":"Biochemistry, Genetics and Molecular Biology","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Total synthesis; Carbazole; Imine; Diene; Quinone; Stereochemistry; Diels–Alder reaction; Core (optical fiber); Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001638792,0.0005823075,0.0004532356,0.0007599617,0.0003742856,0.0003571883,0.000505125,0.000467123,0.002184019],"category_scores_gemma":[0.0002710404,0.000201773,0.0003334037,0.0007142782,0.000324276,0.0003613912,0.000518669,0.0005933625,0.0006083046],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006567351,"about_ca_system_score_gemma":0.0008583128,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001865263,"about_ca_topic_score_gemma":0.002210059,"domain_scores_codex":[0.9998745,0.00001523814,0.0000133584,0.00001990953,0.0000343977,0.00004257424],"domain_scores_gemma":[0.9998958,0.00001004673,0.0000119964,0.00001160904,0.00002636222,0.00004415052],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003790008,0.0002234896,0.0004372531,0.001460755,0.0001027175,0.001049669,0.0005282323,0.002329741,0.9008242,0.007772814,0.002535366,0.08235677],"study_design_scores_gemma":[0.0002415653,0.001789448,0.00310873,0.0001082511,0.00007223383,0.001344694,0.0001592137,0.0009960927,0.8954617,0.001357295,0.09525766,0.0001031083],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8629346,0.02439932,0.02664627,0.0007811629,0.0004875468,0.001311247,0.004542018,0.0004279715,0.07846997],"genre_scores_gemma":[0.959712,0.01118084,0.01476772,0.0003237178,0.00003075804,0.0003595559,0.001540272,0.00004473851,0.01204053],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002184019,"threshold_uncertainty_score":0.007306337,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008772909073207973,"score_gpt":0.2035809885154758,"score_spread":0.1948080794422679,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}