{"id":"W2949093489","doi":"10.1021/jo048854f","title":"Total Synthesis of Ustiloxin D and Considerations on the Origin of Selectivity of the Asymmetric Allylic Alkylation","year":2004,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Tsuji–Trost reaction; Selectivity; Alkylation; Allylic rearrangement; Chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004264951,0.00008432266,0.0001955222,0.00001572967,0.00005786435,0.000005258933,0.0001655006,0.00007362798,0.00006866731],"category_scores_gemma":[0.001367822,0.00004335707,0.0001374674,0.0002091371,0.0001604591,0.000003279888,0.00005447186,0.0001272073,1.532219e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002060811,"about_ca_system_score_gemma":0.0001291373,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001618827,"about_ca_topic_score_gemma":0.000005514378,"domain_scores_codex":[0.9992671,0.00005887198,0.0003346647,0.00007425959,0.0001915478,0.00007354145],"domain_scores_gemma":[0.9987668,0.0003129781,0.0005046126,0.0002366971,0.0001523587,0.00002657951],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003201521,0.00008270887,0.000550577,0.00002237539,0.0001371692,1.595043e-7,0.00003526801,0.0001234142,0.9986942,0.000024635,0.00005875398,0.0002387628],"study_design_scores_gemma":[0.0001669079,0.00003766834,0.002564422,0.00004832543,0.0001780214,0.00005646903,0.00008935591,0.00001076874,0.9964859,0.0002999715,0.00001793811,0.00004419722],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983019,0.000312833,0.0001260913,0.0009295052,0.00001161836,0.00003949802,0.000009173272,7.239266e-7,0.0002686763],"genre_scores_gemma":[0.9996765,0.00014461,0.00005924159,0.00002581904,0.00005915285,5.451899e-7,5.726898e-7,0.000006830742,0.00002672565],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002208207,"threshold_uncertainty_score":0.176805,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008093385017631797,"score_gpt":0.2140965216164912,"score_spread":0.2060031365988594,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}