{"id":"W2949145352","doi":"10.1021/acsearthspacechem.9b00142","title":"Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles","year":2019,"lang":"en","type":"article","venue":"ACS Earth and Space Chemistry","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Division of Atmospheric and Geospace Sciences; U.S. Department of Energy","keywords":"Dimethylamine; Ammonium sulfate; Chemistry; Particle (ecology); Aqueous solution; Sulfate; Ammonium; Phase (matter); Relative humidity; Aqueous two-phase system; Inorganic chemistry; Chemical engineering; Analytical Chemistry (journal); Chromatography; Thermodynamics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001662579,0.0003709893,0.0002829908,0.0001857206,0.000204709,0.0004511579,0.0002902757,0.0002959709,0.0005034927],"category_scores_gemma":[0.0002852366,0.0002064951,0.0005348654,0.0001111164,0.0001831983,0.0003765167,0.0001791844,0.000287129,0.0001324634],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006964778,"about_ca_system_score_gemma":0.0003284186,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.009689982,"about_ca_topic_score_gemma":0.004391761,"domain_scores_codex":[0.9999225,0.000008694499,0.000005364695,0.0000206254,0.00002455941,0.00001822085],"domain_scores_gemma":[0.9998746,0.0000578171,0.00002731591,0.000006019764,0.00002258599,0.00001171367],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004663671,0.0001556813,0.01170543,0.000215407,0.00008889371,0.0002378715,0.0001224283,0.1889409,0.7918883,0.001209595,0.0001300679,0.004839098],"study_design_scores_gemma":[0.00002570949,0.0002732116,0.00485112,0.00000690271,0.00003278259,0.00003547419,0.00004738463,0.7539288,0.2402281,0.0001509506,0.000395585,0.0000240566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967576,0.0001863096,0.002190924,0.00002196162,0.000008421791,0.00001378759,0.0001174008,0.00002777028,0.0006757606],"genre_scores_gemma":[0.9986869,0.0001345918,0.0008104895,0.00000889172,0.000001999751,0.00001076409,0.00007326168,0.00001009185,0.0002631292],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009689982,"threshold_uncertainty_score":0.01926714,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006547979141293675,"score_gpt":0.2291784170287114,"score_spread":0.2226304378874178,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}