{"id":"W2949166827","doi":"10.1002/chin.200643102","title":"Easily Prepared Air‐ and Moisture‐Stable Pd—NHC (NHC: N‐Heterocyclic Carbene) Complexes: A Reliable, User‐Friendly, Highly Active Palladium Precatalyst for the Suzuki—Miyaura Reaction.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Carbene; Palladium; Environmentally friendly; Moisture; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001704802,0.0005588565,0.0005310444,0.00009342659,0.0007969672,0.0002695903,0.0005383415,0.0003660306,0.0001128294],"category_scores_gemma":[0.0001971676,0.000480363,0.0002881465,0.0003112268,0.0003575818,0.0006083314,0.0002232014,0.0004651277,0.00003056422],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007345509,"about_ca_system_score_gemma":0.0001743929,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004778531,"about_ca_topic_score_gemma":0.001179255,"domain_scores_codex":[0.9972485,1.05143e-7,0.000739729,0.0007501536,0.0004465648,0.0008149539],"domain_scores_gemma":[0.997102,0.0005948413,0.0004940823,0.001279315,0.0003275403,0.0002022484],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008849608,0.0003731292,0.001335468,0.001038262,0.0005630236,0.00000826044,0.001666001,0.0001731657,0.9217439,0.0003982404,0.06743015,0.004385386],"study_design_scores_gemma":[0.001459144,0.00003209944,0.002446529,0.0000966249,0.0002801646,0.0001130263,0.001306214,0.0003388831,0.7742816,0.0001496025,0.2189715,0.0005245784],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9374378,0.0006727459,0.00002070094,0.0003574209,0.0003839115,0.0009731111,0.0007916026,0.0005221518,0.05884054],"genre_scores_gemma":[0.9621292,0.0000818403,0.00005751588,0.00006161062,0.0005714399,0.0004502013,0.001359343,0.00009842156,0.03519037],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1515414,"threshold_uncertainty_score":0.9997648,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009887946608825846,"score_gpt":0.2407411519195721,"score_spread":0.2308532053107463,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}