{"id":"W2949166827","doi":"10.1002/chin.200643102","title":"Easily Prepared Air‐ and Moisture‐Stable Pd—NHC (NHC: N‐Heterocyclic Carbene) Complexes: A Reliable, User‐Friendly, Highly Active Palladium Precatalyst for the Suzuki—Miyaura Reaction.","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Carbene; Palladium; Environmentally friendly; Moisture; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002998975,0.0006969423,0.0003209674,0.0004252836,0.0003466795,0.0003979727,0.0009546106,0.0004312565,0.00318859],"category_scores_gemma":[0.0004508409,0.0005080723,0.0001748477,0.0002570388,0.0002772453,0.0006670846,0.0006053771,0.001091894,0.0026354],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003595191,"about_ca_system_score_gemma":0.0003547012,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005235992,"about_ca_topic_score_gemma":0.00198144,"domain_scores_codex":[0.9997324,0.00002934647,0.00002354215,0.00006519107,0.0001092879,0.00004010766],"domain_scores_gemma":[0.999892,0.00001607368,0.00002490195,0.00002360104,0.00001329393,0.00003010167],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001873741,0.00006594087,0.00009890319,0.0003044234,0.00002600451,0.0001750325,0.00005487861,0.0003141411,0.972674,0.0009359614,0.002883109,0.02228028],"study_design_scores_gemma":[0.00003129225,0.0001033862,0.0002616734,0.000006483424,0.00001561146,0.0002538469,0.000008240458,0.0003598562,0.9887632,0.0001298809,0.0100496,0.00001699815],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6936852,0.02815094,0.1930151,0.0009362106,0.0007817543,0.0009223167,0.005378885,0.007278713,0.06985088],"genre_scores_gemma":[0.9265501,0.005981988,0.04075273,0.000162721,0.0001080208,0.0001990527,0.003118059,0.0006232572,0.02250394],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00318859,"threshold_uncertainty_score":0.01066685,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009887946608825846,"score_gpt":0.2407411519195721,"score_spread":0.2308532053107463,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}