{"id":"W2949199690","doi":"10.1002/chin.200342068","title":"Synthesis of Allyl and Alkyl Vinyl Ethers Using an in situ Prepared Air‐Stable Palladium Catalyst. Efficient Transfer Vinylation of Primary, Secondary, and Tertiary Alcohols.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Alkyl; Catalysis; Tertiary alcohols; Palladium; Primary (astronomy); In situ; Organic chemistry; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001529015,0.0004029759,0.0001933258,0.0002504686,0.0001998227,0.0002769566,0.0003214862,0.0003124192,0.004033642],"category_scores_gemma":[0.0002055152,0.0003063024,0.0002137395,0.00020536,0.0001519914,0.0004891435,0.0003074076,0.0005800754,0.001635637],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003064139,"about_ca_system_score_gemma":0.0002782083,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003118639,"about_ca_topic_score_gemma":0.001002551,"domain_scores_codex":[0.9999157,0.0000088397,0.000007705065,0.00001763341,0.00002416876,0.00002580698],"domain_scores_gemma":[0.9999416,0.000008597485,0.00001138641,0.00001056331,0.00000953289,0.00001826477],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001409109,0.00006161335,0.00005672023,0.0001609731,0.0000224685,0.0001635163,0.0000488938,0.0003689123,0.9763708,0.002432148,0.0006830954,0.01948998],"study_design_scores_gemma":[0.00002231335,0.00007617602,0.0001467248,0.000004937074,0.000009479929,0.0001147888,0.00001113351,0.0004201141,0.9901715,0.0003370686,0.008679463,0.000006266393],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8240371,0.01285066,0.07375548,0.0008061586,0.0006170966,0.0002870309,0.002597768,0.0008192527,0.08422939],"genre_scores_gemma":[0.9556658,0.003507424,0.01576746,0.00007716251,0.00003134724,0.00005585907,0.0009906385,0.00009867467,0.0238056],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004033642,"threshold_uncertainty_score":0.0134939,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0110734016619424,"score_gpt":0.2218768151395048,"score_spread":0.2108034134775624,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}