{"id":"W2949201141","doi":"10.1002/chin.200602065","title":"Iodomethylzinc Phosphates: Powerful Reagents for the Cyclopropanation of Alkenes.","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Cyclopropanation; Library science; Humanities; Art history; Philosophy; Art; Computer science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001567089,0.0001364201,0.0001393367,0.0000340747,0.00007683485,0.00001950736,0.0002742,0.0001183136,0.001731457],"category_scores_gemma":[0.0001697184,0.0001072085,0.0001347077,0.0001115944,0.00005005722,0.0001559448,0.00005036498,0.000100469,0.00006310957],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000917455,"about_ca_system_score_gemma":0.0000512053,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001284546,"about_ca_topic_score_gemma":0.00001618274,"domain_scores_codex":[0.9990435,1.852003e-7,0.0003311416,0.0001566117,0.000258755,0.0002097721],"domain_scores_gemma":[0.9990126,0.0001570702,0.000241216,0.0003777714,0.0001583625,0.00005291507],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008195038,0.00004753339,0.00002145896,0.0002615905,0.00006520894,3.401175e-7,0.0008342929,0.00001166622,0.140633,0.0006341609,0.003662313,0.8537465],"study_design_scores_gemma":[0.0004259861,0.000009967849,0.00001774222,0.00001935284,0.00003299198,0.000005371156,0.000612337,0.0001514173,0.712709,0.00005822769,0.2858672,0.00009042129],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.09032792,0.001651028,0.0003293559,0.0005810696,0.0003847809,0.0005048921,0.0001074617,0.0002119756,0.9059015],"genre_scores_gemma":[0.9811754,0.0002420342,0.0009638883,0.0001086087,0.0003327094,0.00009945699,0.0001401083,0.00003814733,0.0168996],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8908475,"threshold_uncertainty_score":0.9991811,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01458003083129062,"score_gpt":0.25474285528483,"score_spread":0.2401628244535394,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}