{"id":"W2949204916","doi":"10.1002/chin.200821102","title":"ChemInform Abstract: Stereoselective Isomerization of N‐Allyl Aziridines into Geometrically Stable Z‐Enamines Using Rhodium Hydride Catalysis.","year":2008,"lang":"en","type":"article","venue":"ChemInform","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Isomerization; Stereoselectivity; Hydride; Rhodium; Catalysis; Combinatorial chemistry; Medicinal chemistry; Organic chemistry; Hydrogen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000194417,0.0003968317,0.0006360853,0.0006919059,0.0002332134,0.00003828861,0.0004820311,0.0002821977,0.00178721],"category_scores_gemma":[0.0006862748,0.0003894603,0.0002976156,0.00295344,0.0001986435,0.0007535198,0.0001658342,0.0002318491,0.00004562045],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004085852,"about_ca_system_score_gemma":0.0002674722,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003551808,"about_ca_topic_score_gemma":0.00001386189,"domain_scores_codex":[0.9973043,1.531967e-7,0.001034616,0.0004017715,0.00077405,0.0004850856],"domain_scores_gemma":[0.9976435,0.0001597931,0.000781534,0.0005764673,0.0006133249,0.00022534],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001780481,0.0006780555,0.004453334,0.001188378,0.0009592429,0.00002936809,0.005268326,0.0001144593,0.5597684,0.00007339344,0.004865031,0.422424],"study_design_scores_gemma":[0.0006402722,0.00001732158,0.000411287,0.00003435089,0.0001231461,0.00004286537,0.0005925671,0.0006352657,0.9883185,0.0000207664,0.008726832,0.000436815],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.523728,0.0003576305,0.00006153622,0.00003671723,0.00006515775,0.0001339899,0.00004455756,0.0001506207,0.4754218],"genre_scores_gemma":[0.9787082,0.0001952579,0.0002543956,0.00005758545,0.0001484048,0.00002725825,0.000738421,0.00004659266,0.01982388],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4555979,"threshold_uncertainty_score":0.9998558,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01825243443756167,"score_gpt":0.2423056899807185,"score_spread":0.2240532555431568,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}