{"id":"W2949206543","doi":"10.1002/chin.200330041","title":"Bis(oxazoline)×Copper(I)‐Catalyzed Enantioselective Cyclopropanation of Cinnamate Esters with Diazomethane.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Chemistry; Oxazoline; Diazomethane; Enantioselective synthesis; Catalysis; Copper; Organic chemistry; Propionates; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001537783,0.0002998251,0.0003567662,0.0001607854,0.00007456683,0.00002723098,0.0001978362,0.0001783765,0.0005335955],"category_scores_gemma":[0.0001643194,0.0002532564,0.0001061236,0.0004672901,0.00009019726,0.0002945302,0.00003107339,0.0002272239,0.00002717661],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001866902,"about_ca_system_score_gemma":0.000210908,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003368361,"about_ca_topic_score_gemma":0.0000520782,"domain_scores_codex":[0.9984005,0.000001236275,0.000445242,0.0003320007,0.0004387814,0.0003822404],"domain_scores_gemma":[0.9986411,0.00006303399,0.0003917434,0.0004594577,0.0003127558,0.0001318838],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001599406,0.0000994631,0.0007546076,0.0006965537,0.0001593893,0.00001028536,0.001477252,0.000011206,0.9483585,0.001273133,0.0001567135,0.04684294],"study_design_scores_gemma":[0.001275195,0.00003714043,0.0000682067,0.00009767429,0.00006428209,0.00008383684,0.002257288,0.00001441754,0.986869,0.00005417746,0.008852571,0.0003261487],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5469208,0.00009021191,0.00008016307,0.00002233579,0.00008348858,0.0001963543,0.00003886264,0.0001673078,0.4524005],"genre_scores_gemma":[0.9958394,0.0000551738,0.0007294862,0.00002099744,0.00004387247,0.00006271974,0.0002336178,0.00005284526,0.002961888],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4494386,"threshold_uncertainty_score":0.999992,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008857014351971747,"score_gpt":0.2186981965841584,"score_spread":0.2098411822321866,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}