{"id":"W2949222899","doi":"10.1002/chin.200728074","title":"A Pronounced Anionic Effect in the Pd‐Catalyzed Buchwald—Hartwig Amination Reaction Revealed in Phosphonium Salt Ionic Liquids.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Phosphonium; Phosphonium salt; Amination; Salt (chemistry); Catalysis; Ionic liquid; Combinatorial chemistry; Ionic bonding; Organic chemistry; Medicinal chemistry; Polymer chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001765306,0.0003059518,0.0003181364,0.0001967026,0.0001369973,0.0001023982,0.0003928226,0.0003279283,0.0001068778],"category_scores_gemma":[0.0006413937,0.0002644687,0.0001424435,0.0008382749,0.0001174877,0.000429291,0.00006721405,0.0007419801,0.000129962],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001792948,"about_ca_system_score_gemma":0.0001771424,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005982685,"about_ca_topic_score_gemma":0.001017525,"domain_scores_codex":[0.9978065,3.594888e-7,0.0007266364,0.0004118906,0.0004491801,0.0006054149],"domain_scores_gemma":[0.9982702,0.0005310701,0.0002851148,0.0007367142,0.00009374799,0.00008313476],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005154223,0.0002941253,0.002547774,0.0003902884,0.00002620959,0.00002700493,0.00341247,0.00000655857,0.9602871,0.00008613933,0.0008595576,0.03154735],"study_design_scores_gemma":[0.002086229,0.00003847768,0.0221092,0.0002146868,0.00003133637,0.00007790158,0.0007575164,0.0001785908,0.9723119,0.00007638134,0.001793166,0.0003245914],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9736257,0.0001038301,0.000002535029,0.0001692877,0.0001768214,0.0004779887,0.00001023978,0.0001392927,0.02529431],"genre_scores_gemma":[0.9969708,0.00003972495,0.000006479439,0.00005422561,0.0001779169,0.0002117385,0.0004968874,0.00003543092,0.002006773],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03122275,"threshold_uncertainty_score":0.9999807,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007729699016821934,"score_gpt":0.2642667070185624,"score_spread":0.2565370080017405,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}