{"id":"W2949242867","doi":"10.1002/chin.201051224","title":"ChemInform Abstract: Pd‐PEPPSI Complexes and the Negishi Reaction","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Negishi coupling; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002679784,0.0002508103,0.0002547369,0.00003744638,0.0003158627,0.0002405999,0.0003154565,0.0002565195,0.001970653],"category_scores_gemma":[0.000410137,0.0001914527,0.0001350338,0.0001152798,0.0007455123,0.0004166043,0.0001354297,0.0008441861,0.0001356707],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007812586,"about_ca_system_score_gemma":0.00007695208,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003252959,"about_ca_topic_score_gemma":0.0001148881,"domain_scores_codex":[0.9987027,2.540722e-9,0.0004130071,0.0002496718,0.0002838332,0.0003508052],"domain_scores_gemma":[0.9984254,0.0003387634,0.0002502146,0.0007264645,0.0001092721,0.0001499289],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001213315,0.00004420468,0.00008381917,0.000146099,0.00005398721,0.000002533465,0.001224583,7.179194e-8,0.8338438,0.001745678,0.0145392,0.1481947],"study_design_scores_gemma":[0.001350312,0.000002639714,0.001163063,0.00002496435,0.0000468552,0.0002033666,0.0007531203,0.00004485769,0.8107008,0.0003888563,0.1850765,0.0002446079],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.454854,0.00002800932,3.074742e-8,0.0003256663,0.0001920215,0.00008135819,0.00002146976,0.0001453265,0.5443521],"genre_scores_gemma":[0.9582001,0.000039408,0.000006082767,0.0001002693,0.0004736543,0.00005087531,0.0001585221,0.0000290094,0.04094207],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.50341,"threshold_uncertainty_score":0.9989417,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01221502475817784,"score_gpt":0.254391146102758,"score_spread":0.2421761213445801,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}