{"id":"W2949260094","doi":"10.1021/ol0165995","title":"An Unexpected Paternò-B chi Reaction in the Crystalline State","year":2001,"lang":"en","type":"article","venue":"Organic Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Alkene; Hydrogen atom abstraction; Solid-state; Aryl; Aldehyde; Cleavage (geology); Crystal structure; Photochemistry; Hydrogen; Organic chemistry; Physical chemistry; Catalysis; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008091985,0.0002992569,0.0001231724,0.0001546934,0.000305003,0.0004022852,0.0003401961,0.000318075,0.003444421],"category_scores_gemma":[0.0001751824,0.0001778624,0.0001117438,0.0001550461,0.000366005,0.0004462071,0.0002266681,0.0006244131,0.0006936011],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002599172,"about_ca_system_score_gemma":0.0002741443,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007541828,"about_ca_topic_score_gemma":0.001011669,"domain_scores_codex":[0.9999341,0.000007920134,0.000002080264,0.00002031216,0.00001836717,0.00001734366],"domain_scores_gemma":[0.9999442,0.00001320542,0.00001050778,0.00001199365,0.000008259173,0.00001185688],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002464947,0.0001049526,0.001214436,0.0003571405,0.00005372233,0.001473658,0.0002817559,0.000426036,0.9457518,0.02670891,0.006473147,0.01690789],"study_design_scores_gemma":[0.00004480596,0.0003583846,0.00204627,0.00001373432,0.00002213587,0.001607133,0.00009125522,0.001104853,0.9718888,0.002155733,0.02064848,0.00001842147],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8710869,0.005945141,0.02377117,0.00112721,0.0005522501,0.0001449909,0.001076395,0.0005926028,0.09570339],"genre_scores_gemma":[0.989369,0.001168135,0.001860986,0.0001426137,0.00002916035,0.00003339784,0.0003067643,0.00002708134,0.007062876],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003444421,"threshold_uncertainty_score":0.01152277,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0103414740474856,"score_gpt":0.2314300771441875,"score_spread":0.2210886030967019,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}