{"id":"W2949263468","doi":"10.1002/0471264180.or073.01","title":"Allylboration of Carbonyl Compounds","year":2009,"lang":"en","type":"book","venue":"Organic reactions","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Reagent; Chemistry; Allylic rearrangement; Stereoselectivity; Organic chemistry; Alkene; Enantioselective synthesis; Nucleophile; Context (archaeology); Combinatorial chemistry; Organic synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005652504,0.0002627034,0.0004209747,0.00008268153,0.0001052711,0.00002535228,0.0002017235,0.0006003256,0.005310192],"category_scores_gemma":[0.00008057974,0.0002569719,0.0002456779,0.0001038444,0.00008287299,0.00006484937,0.00003073443,0.0005730707,0.0001199871],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000472898,"about_ca_system_score_gemma":0.0003900932,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004231671,"about_ca_topic_score_gemma":0.00004343997,"domain_scores_codex":[0.9986919,0.000007366566,0.0005169282,0.0003166429,0.0002885878,0.0001785771],"domain_scores_gemma":[0.9985754,0.0001645738,0.0004474953,0.0005819426,0.0001313451,0.00009927173],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000005129775,0.0001439297,0.000003462251,0.0001016692,0.0001271977,0.000002268249,0.0000271965,0.00000106626,0.9338019,0.001442222,0.06150377,0.002840183],"study_design_scores_gemma":[0.0001247125,0.00001091071,0.00002495695,0.0002162721,0.0002254232,0.00003216196,0.00002036371,0.000009347501,0.1579646,0.002478457,0.8386251,0.0002676743],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.0004411173,0.0002325554,0.00002482184,0.0002509815,0.0001207551,0.00005933659,0.00007511055,0.000136363,0.998659],"genre_scores_gemma":[0.04375883,0.0004987258,0.000109169,0.00002455213,0.0007617445,0.000008449479,0.000484044,0.00007357622,0.9542809],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.7771213,"threshold_uncertainty_score":0.9999883,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01016371338654704,"score_gpt":0.2163362033053108,"score_spread":0.2061724899187637,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}