{"id":"W2949271561","doi":"10.1021/ja993427i","title":"Palladium-Catalyzed Enantioselective Alkylative Ring Opening","year":2000,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":161,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Citation; Enantioselective synthesis; Ring (chemistry); Icon; Computer science; Library science; Chemistry; World Wide Web; Information retrieval; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006984866,0.0008556613,0.0005696974,0.0005302404,0.0004775868,0.0006422826,0.001224446,0.0004845224,0.008169997],"category_scores_gemma":[0.0004836206,0.000402462,0.0006071824,0.0006238091,0.000426124,0.001136623,0.001253342,0.002202489,0.003523129],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006852282,"about_ca_system_score_gemma":0.0007208621,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001097957,"about_ca_topic_score_gemma":0.002754854,"domain_scores_codex":[0.9990754,0.0001034052,0.0000706824,0.0001765402,0.0001893859,0.0003846824],"domain_scores_gemma":[0.9998356,0.00003579304,0.00003766377,0.00003672188,0.00002636252,0.0000278707],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008859433,0.001246847,0.001001106,0.00358966,0.0004130907,0.004289547,0.001075585,0.006228965,0.7178127,0.03182469,0.05585362,0.1757782],"study_design_scores_gemma":[0.0002181412,0.00097757,0.001422938,0.0001156196,0.0001097581,0.001351923,0.0001468809,0.008424186,0.9057637,0.002500364,0.07885328,0.0001155135],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5444915,0.01493874,0.1146562,0.003502814,0.002443018,0.001464805,0.007101232,0.004212673,0.3071891],"genre_scores_gemma":[0.9397303,0.01149284,0.01973233,0.0006085138,0.0001504731,0.0001703146,0.00132725,0.0001960494,0.02659186],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008169997,"threshold_uncertainty_score":0.02733141,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0086847935376497,"score_gpt":0.2375416186756119,"score_spread":0.2288568251379622,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}