{"id":"W2949298005","doi":"10.1002/chin.201024179","title":"ChemInform Abstract: Preparation of a Storable Zinc Carbenoid Species and Its Application in Cyclopropanation, Chain Extension, and [2,3]‐Sigmatropic Rearrangement Reactions.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Carbenoid; Chemistry; Cyclopropanation; Extension (predicate logic); Sigmatropic reaction; Zinc; Combinatorial chemistry; Service (business); Stereochemistry; Organic chemistry; Catalysis; Rhodium; Computer science; Business; Programming language","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002190275,0.0004936057,0.0001978046,0.0003698979,0.0003250225,0.000325157,0.0005530579,0.0003058127,0.007268776],"category_scores_gemma":[0.0002359882,0.0001789764,0.0001899453,0.0003752974,0.0002568509,0.0005518731,0.0004330749,0.0006132632,0.00181071],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003685468,"about_ca_system_score_gemma":0.0005219392,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009488115,"about_ca_topic_score_gemma":0.00110386,"domain_scores_codex":[0.9998912,0.000008551146,0.00000687707,0.00002754553,0.00003733135,0.00002855878],"domain_scores_gemma":[0.9999497,0.000007778882,0.00001192294,0.000009726728,0.00000799077,0.00001288448],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006944785,0.0001299598,0.0002454193,0.0005932219,0.00003420839,0.0003313096,0.0001242444,0.0009123826,0.9448395,0.005990279,0.00581317,0.04029185],"study_design_scores_gemma":[0.0001167171,0.0005726627,0.0005747185,0.00002698268,0.0000224431,0.0002487602,0.00002053286,0.000999746,0.9751483,0.000517316,0.02173044,0.00002143788],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7871121,0.0138468,0.07820988,0.00132106,0.0009493192,0.0007765657,0.004942165,0.00198307,0.110859],"genre_scores_gemma":[0.9558796,0.005521424,0.01217158,0.0002108722,0.0000926942,0.0001206882,0.001854821,0.0001534236,0.02399495],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007268776,"threshold_uncertainty_score":0.02431649,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01027153274188398,"score_gpt":0.241878486980764,"score_spread":0.23160695423888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}