{"id":"W2949331685","doi":"10.1002/chin.201312035","title":"ChemInform Abstract: Pd‐PEPPSI‐IPent<sup>Cl</sup>: A Highly Effective Catalyst for the Selective Cross‐Coupling of Secondary Organozinc Reagents.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Halide; Aryl; Reagent; Catalysis; Selectivity; Coupling (piping); Combinatorial chemistry; Inorganic chemistry; Organic chemistry; Alkyl; Metallurgy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001538407,0.000541909,0.0001807318,0.0003733663,0.0002028983,0.000309507,0.0004502212,0.000306911,0.009213747],"category_scores_gemma":[0.0001707428,0.0001894833,0.00009987992,0.0002821099,0.0002265421,0.0003343251,0.0003052433,0.0005409686,0.003766703],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000355473,"about_ca_system_score_gemma":0.0003420059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006602386,"about_ca_topic_score_gemma":0.0004461567,"domain_scores_codex":[0.9999022,0.00001027112,0.000005173193,0.00002318362,0.00004123935,0.00001789571],"domain_scores_gemma":[0.9999664,0.000007602812,0.000007286966,0.000003647841,0.000008878989,0.000006274967],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0010507,0.00010484,0.0004532254,0.0009565745,0.00004543117,0.0004264156,0.00006806753,0.001216858,0.8951226,0.005166113,0.01484277,0.08054624],"study_design_scores_gemma":[0.00003891867,0.00008538677,0.000473098,0.00001107911,0.00002221475,0.0002911291,0.000008815165,0.0005261931,0.9746615,0.0001710959,0.02370519,0.000005422286],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6359372,0.01440908,0.07692403,0.002310018,0.000606394,0.0004006418,0.01061377,0.004962447,0.2538363],"genre_scores_gemma":[0.9531846,0.004297812,0.01086195,0.0002092145,0.00005684021,0.00006203921,0.004155098,0.0002242455,0.02694828],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009213747,"threshold_uncertainty_score":0.03082305,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009472763465360247,"score_gpt":0.257022621154576,"score_spread":0.2475498576892157,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}