{"id":"W2949337971","doi":"10.1002/chin.201145079","title":"ChemInform Abstract: One‐Step Entry to P,O‐ and P,N‐Type Heterocyclic Tertiary Phosphine Ligands and Application in Suzuki—Miyaura Cross‐Coupling Reactions.","year":2011,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Phosphine; Coupling reaction; Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001808881,0.0003423784,0.0003228617,0.000137093,0.0001820085,0.0001603393,0.0002306502,0.0003284293,0.0003948673],"category_scores_gemma":[0.0001606155,0.000381269,0.00006405324,0.000288136,0.0001788168,0.0005770598,0.0002115987,0.0004611057,0.00007694669],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002649557,"about_ca_system_score_gemma":0.00004874428,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006900058,"about_ca_topic_score_gemma":0.0001018713,"domain_scores_codex":[0.9980478,3.115725e-9,0.0007258808,0.0005069886,0.0002407428,0.0004785727],"domain_scores_gemma":[0.9986244,0.00009775048,0.0002417918,0.0006230751,0.0001128943,0.0003001194],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000259804,0.0002517395,0.02997992,0.0007065206,0.00006607335,0.000008691143,0.002833025,0.000003666803,0.8556638,0.00005928661,0.0005480174,0.1096194],"study_design_scores_gemma":[0.0007911651,0.00001459895,0.05104728,0.0001694936,0.00003280968,0.00007143161,0.0003709328,0.0002883518,0.9428283,0.00006088293,0.003902506,0.0004222697],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9500854,0.0001844657,9.543561e-7,0.00005640297,0.00007970081,0.0002191616,0.00001955522,0.0001714336,0.04918292],"genre_scores_gemma":[0.9942955,0.0002125827,0.00003696654,0.00008087554,0.0001412613,0.0001166508,0.0001545508,0.00004859365,0.004913053],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1091972,"threshold_uncertainty_score":0.9998639,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01644797957140467,"score_gpt":0.2622549129188493,"score_spread":0.2458069333474446,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}