{"id":"W2949342213","doi":"10.1002/chin.200248255","title":"Proton and MetalI‐Ion Activation of C—H Exchange in Five‐Membered Azoles","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Proton; Stereochemistry; Medicinal chemistry; Nuclear physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001245841,0.00009221144,0.00014519,0.00006664843,0.00004112057,0.000007050406,0.00006173076,0.0001657245,0.001718197],"category_scores_gemma":[0.00007497496,0.00008367379,0.00003213976,0.000137838,0.00009992113,0.0001680666,0.00003904208,0.0002270138,0.00001511731],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000390831,"about_ca_system_score_gemma":0.000007268194,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002908659,"about_ca_topic_score_gemma":0.000005189649,"domain_scores_codex":[0.9994774,0.000002073429,0.0002055791,0.0001048683,0.0000638955,0.0001461124],"domain_scores_gemma":[0.9996486,0.00009322546,0.00008682249,0.00007986036,0.00003151214,0.00005997036],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001598875,0.0003684313,0.002303391,0.000470688,0.00006090648,0.000002489633,0.003175957,0.000002532754,0.4530459,0.0003071389,0.01065197,0.5294507],"study_design_scores_gemma":[0.0006425655,0.00002345178,0.0005953412,0.00001951469,0.00001374332,0.000003545819,0.0001144989,0.0005330546,0.7812144,0.00006560301,0.2166983,0.000076023],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8189211,0.0002753891,5.262519e-7,0.0002378448,0.00006689189,0.000357443,0.000008068978,0.00001950259,0.1801132],"genre_scores_gemma":[0.9949206,0.0005781699,0.00002099354,0.0001472436,0.0000484591,0.00009958679,0.00001579903,0.000006154102,0.004162957],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5293747,"threshold_uncertainty_score":0.9991944,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1151768369903686,"score_gpt":0.388239351819207,"score_spread":0.2730625148288385,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}