{"id":"W2949351932","doi":"10.1021/ol403550b","title":"Chelation-Assisted Photoelimination of B,N-Heterocycles","year":2013,"lang":"en","type":"article","venue":"Organic Letters","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts","keywords":"Chemistry; Chelation; Combinatorial chemistry; Phosphorescence; Metal; Quantum chemical; Molecule; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001163613,0.0001711032,0.0001664535,0.0001159074,0.0001560459,0.000158236,0.0002387911,0.0002036383,0.001473991],"category_scores_gemma":[0.0001290156,0.0000793311,0.00008453699,0.00008904356,0.0001342927,0.0001888117,0.0002356581,0.000238884,0.0003373428],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002817299,"about_ca_system_score_gemma":0.0001276195,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003493548,"about_ca_topic_score_gemma":0.0008663991,"domain_scores_codex":[0.9999272,0.00001247964,0.000004000245,0.00001995678,0.00001299447,0.0000233594],"domain_scores_gemma":[0.999953,0.00001194342,0.00001156686,0.000006948764,0.000005603257,0.00001092056],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001369084,0.00002349565,0.00008158618,0.00006341256,0.000004271913,0.000079181,0.00003127302,0.0002624973,0.9946814,0.0007156496,0.0001823023,0.003737978],"study_design_scores_gemma":[0.00001425503,0.0001291779,0.0003602139,0.000003025626,0.000002692852,0.00007119816,0.000006453548,0.0004392999,0.9971911,0.0000530889,0.001725269,0.000004115235],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891512,0.0007704798,0.002766263,0.00007782416,0.00002459221,0.0000262568,0.0000952016,0.0001101161,0.006977973],"genre_scores_gemma":[0.9953607,0.0003575147,0.001528827,0.00004632495,0.000007105746,0.00002142063,0.00007121645,0.00001865014,0.002588244],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001473991,"threshold_uncertainty_score":0.004930973,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007526104269950891,"score_gpt":0.202126211741431,"score_spread":0.1946001074714801,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}