{"id":"W2949358406","doi":"10.1002/chin.200115023","title":"ChemInform Abstract: First Examples of Thallium Chalcogenide Cages. Syntheses, <sup>77</sup>Se, <sup>203</sup>Tl, and <sup>205</sup>Tl NMR Study of the Tl<sub>4</sub>Se<sub>5</sub><sup>4‐</sup> and Tl<sub>4</sub>Se<sub>6</sub><sup>4‐</sup> Anions, the X‐Ray Crystal Structure of (2,2,2‐crypt‐K<sup>+</sup>) <sub>3</sub>Tl<sub>5</sub>Se<sub>5</sub><sup>3‐</sup>, and Theoretical Studies.","year":2001,"lang":"en","type":"article","venue":"ChemInform","topic":"Inorganic Chemistry and Materials","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Thallium; Chemistry; Chalcogenide; Radiochemistry; Nuclear chemistry; Physical chemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","open_science","research_integrity"],"category_scores_codex":[0.007578626,0.0119134,0.0128876,0.002307027,0.005594679,0.002590887,0.009303927,0.008241341,0.001389055],"category_scores_gemma":[0.008694009,0.01070349,0.004323891,0.005711621,0.01225881,0.005469575,0.008826307,0.008792992,0.0003223915],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.003248324,"about_ca_system_score_gemma":0.003292219,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005029337,"about_ca_topic_score_gemma":0.0004535032,"domain_scores_codex":[0.9544266,0.0005504092,0.01484434,0.00995377,0.009168177,0.01105675],"domain_scores_gemma":[0.9616416,0.008783396,0.008286593,0.01176835,0.004579608,0.004940452],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.005284859,0.004266254,0.001631827,0.01140417,0.007535121,0.0008969955,0.04177156,0.005237908,0.8737685,0.0008533146,0.01816421,0.0291853],"study_design_scores_gemma":[0.01598603,0.00143891,0.001069153,0.004607682,0.005780037,0.00401641,0.0449384,0.005001882,0.9006149,0.001824965,0.005230778,0.009490862],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.961574,0.006179061,0.00002902699,0.001153354,0.0007575656,0.009102907,0.01045308,0.001775711,0.008975359],"genre_scores_gemma":[0.9640113,0.02193411,0.0001928825,0.001014851,0.004764262,0.001965574,0.003489475,0.002357603,0.000269978],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0268464,"threshold_uncertainty_score":0.9996562,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01822150104330932,"score_gpt":0.2337034630228144,"score_spread":0.2154819619795051,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}