{"id":"W2949360647","doi":"10.1002/chin.201305041","title":"ChemInform Abstract: Direct Amidation of Carboxylic Acids Catalyzed by ortho‐Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect.","year":2013,"lang":"en","type":"article","venue":"ChemInform","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Catalysis; Halogen; Scope (computer science); Carboxylic acid; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003933252,0.0006718356,0.0002249266,0.0003111772,0.0001955139,0.0002080348,0.0003086801,0.0003239027,0.003828865],"category_scores_gemma":[0.0001805134,0.0002002808,0.0001854549,0.0002292823,0.0002337575,0.0002768993,0.0002390342,0.0004075195,0.001254887],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002344825,"about_ca_system_score_gemma":0.0004976151,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004934648,"about_ca_topic_score_gemma":0.001097307,"domain_scores_codex":[0.9998233,0.00002713762,0.00001102176,0.00003040698,0.0000482028,0.00006003835],"domain_scores_gemma":[0.9999201,0.00001207557,0.00002218566,0.000009980844,0.00001528733,0.00002042148],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004174754,0.0000569494,0.0002025809,0.0002156253,0.00001527244,0.0001383817,0.00002744455,0.0001541213,0.9915308,0.0007170264,0.0005068021,0.006017591],"study_design_scores_gemma":[0.00002849187,0.0002179945,0.0004956895,0.000005435757,0.00001470483,0.0001473737,0.000005897538,0.0002257021,0.9962792,0.00005262764,0.00251949,0.000007451711],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.920638,0.005102441,0.03957608,0.0005035789,0.0002137624,0.0002656571,0.001910452,0.0005406947,0.0312494],"genre_scores_gemma":[0.980253,0.002879291,0.009894261,0.0001203448,0.00002846119,0.00005140359,0.001344976,0.00005511267,0.005373092],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003828865,"threshold_uncertainty_score":0.0128088,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00511731780377547,"score_gpt":0.2248873230000389,"score_spread":0.2197700051962634,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}