{"id":"W2949377817","doi":"10.1002/chin.200319042","title":"Allylsilane‐Modified Amino Acids from the Claisen Rearrangement.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Botanical Research and Chemistry","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Claisen rearrangement; Carroll rearrangement; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002891333,0.0007785937,0.0003204947,0.0003944628,0.0003611059,0.0003312881,0.0006266999,0.0006264911,0.006996069],"category_scores_gemma":[0.0003883657,0.0002629052,0.0002856151,0.0003848651,0.0003201066,0.0008779638,0.0007352547,0.001304841,0.002754146],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004195353,"about_ca_system_score_gemma":0.0006189484,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004761293,"about_ca_topic_score_gemma":0.001613348,"domain_scores_codex":[0.9998268,0.0000265633,0.000009774777,0.00002915211,0.00004089076,0.00006676262],"domain_scores_gemma":[0.9999163,0.00001402987,0.00001793739,0.00001490119,0.00001370526,0.00002318789],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006349757,0.0001810513,0.0002185324,0.001005956,0.00009545491,0.001008181,0.0003062321,0.001954065,0.9340445,0.01262836,0.004713058,0.04320955],"study_design_scores_gemma":[0.0001186101,0.0006723526,0.0008696956,0.00008185714,0.00005053635,0.0007195131,0.00004931899,0.0008883293,0.9468992,0.002593817,0.04700702,0.00004970515],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7659748,0.02888069,0.05109235,0.001923819,0.00168358,0.0005445567,0.00208509,0.0008815773,0.1469335],"genre_scores_gemma":[0.9489596,0.01352675,0.01024076,0.0003804514,0.0001528097,0.0002052309,0.002129649,0.0001289999,0.02427584],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006996069,"threshold_uncertainty_score":0.02340418,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02926661704962993,"score_gpt":0.2334504023623649,"score_spread":0.2041837853127349,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}